Being an unapologetic fan of romance and superhero comics, I like to think I understand the dynamics of superhero couples better than most. Some, like Superman and Lois Lane, will always be iconic. They’re defined by how strong and ideal their love is in the face of overwhelming forces. There’s certainly a place for couples like that in comics.

Then, there’s Spider-Man and Black Cat. In terms of romance, they’re one of those couples who are like nitro and glycerin. Alone, they’re stable in their own right. Put them together, though, and things get volatile. Sometimes, it’s sexy. Sometimes, it’s literal. Most of the time, it ends badly, even by Spider-Man’s defining Parker Luck standards.

However, it’s because their relationship is so volatile that it’s also a lot of fun to follow. If ever you needed proof of that, “Black Cat Annual #1” should make that point beyond a reasonable doubt. In one single comic, you see why Spider-Man and Black Cat have such unique chemistry, yet still frustrate one another in the most adorable way possible.

You don’t have to be a romance fan to appreciate it, but it certainly helps. While “Black Cat Annual #1” is entirely a love story, it dares to have fun with a historically volatile relationship.

The story is billed as the wedding between Spider-Man and Black Cat. To all the Mary Jane Watson fans out there, as well as those not familiar with the dynamics between these two, there’s no need to worry. I won’t spoil much, but I will spoil that the wedding isn’t exactly traditional, even by superhero standards.

The wedding is just part of a more elaborate plot hatched by Black Cat. She just ropes Spider-Man into it because it involves dangerous criminal organizations like the Maggie. He’s reluctant. He’s not thrilled about it. Even his usual wisecracks are somewhat tempered. He still does it, though. That’s the kind of effect Cat has on him.

It’s not healthy, but it’s hardly the most toxic relationship Spider-Man has had over the years. This is a guy second only to Wolverine in terms of getting caught up in unhealthy relationships, some more so than others. While Black Cat might not bring out the worst in him, she’s more capable than most at getting him involved in less-than-heroic endeavors.

In this case, the wedding is almost secondary. Initially, it looks like Black Cat is just looking to steal from the Maggie and humiliate them while looking good in a wedding dress. Even for Cat, that’s pretty ambitious. However, as her plan and its many dangers unfold, her motivations aren’t quite as clear cut.

Writer Jed MacKay nicely captures Black Cat’s persona and motivations. She’s still a thief at heart. That, she doesn’t run from. On the surface, she’s cunning, sassy, and manipulative. However, she’s not a thief in the same mold as Spider-Man’s other villains. She doesn’t steal food from orphans and chuck it in the East River.

MacKay balances out her sass with some genuinely respectable goals. Even Spider-Man cannot deny that. While he’s still not thrilled with her methods or the fact that she roped him into a wedding ceremony, he still gives Black Cat his tenuous trust and she rewards that trust, for the most part.

There’s plenty of banter. There’s also plenty of quips and complaining on Spider-Man’s part. That doesn’t stop Black Cat from having fun with him, even as they face danger and deceit every step of the way. By the end, she clearly has had more fun than Spider-Man.

It’s a fitting summation of their relationship. They have chemistry. They genuinely care about one another. They also work well together. At the same time, they really push each other’s buttons, get on each other’s nerves, and have them do things they prefer not to do. It can make for a volatile and sexy romance, but it’ll never be stable.

MacKay captures the best parts of that dynamic in “Black Cat Annual #1” and fits it into one of Black Cat’s more creative heists. It all comes together perfectly in a single comic, complete with a beautiful cover by J. Scott Campbell and incredible interior artwork by the likes of Natacha Bustos, Juan Gedeon, and Joey Vazquez.

“Black Cat Annual #1” will not convince you that Peter Parker and Felicia Hardy are star-crossed lovers in the mold of Superman and Lois Lane. However, it does nicely demonstrate that there’s plenty of room for a different kind of romance in superhero comics.

It doesn’t have to be a classic love story. It doesn’t have to be totally toxic, either. There’s a lot of gray area in between. Spider-Man and Black Cat occupy a unique spot in that area. They can team up. They can oppose one another. They can even love one another. All this is possible due to the unique dynamics between them. That’s what make them a special kind of superhero couple.

While “Black Cat Annual #1” didn’t give us a true, full-fledged wedding, it offered plenty of fun for these volatile ex-lovers. At the very least, this phony wedding went a lot better than the wedding between Kitty Pryde and Colossus.