Light microscopy of the TS, showing its layered structure from the macroscale to the microscale. (A) Photographs of the TS showing damage to the upper part of the scroll (left). The reverse side of the preserved section (right) shows the follicle pattern of the hairs removed from the skin, which indicated that the text is written on the flesh side of the treated skin. [(A): Courtesy of the Estate of Yigael Yadin.] (B) Column 54 of the unrolled TS. The enlarged inclusion (inset) shows that some parts of the bright, text-carrying inorganic layer have been detached. [(B): Photo credit: The Israel Museum, Jerusalem.] (C) Fragment of TS showing inorganic layer on text side (left) and reverse side (right). The organic layer has partially detached, revealing the inner surface of the inorganic layer. (D) The same fragment in light transmittance from the back differentiating the thinner lower part, where the detachment has occurred from the thicker upper part. (E) Enlarged optical micrograph of the boxed region in (C). Credit: Science Advances (2019). https://advances.sciencemag.org/content/5/9/eaaw7494

First discovered in 1947 by Bedouin shepherds looking for a lost sheep, the ancient Hebrew texts known as the Dead Sea Scrolls are some of the most well-preserved ancient written materials ever found. Now, a study by researchers at MIT and elsewhere elucidates a unique ancient technology of parchment making and provides potentially new insights into methods to better preserve these precious historical documents.

The study focused on one scroll in particular, known as the Temple Scroll, among the roughly 900 full or partial scrolls found in the years since that first discovery. The scrolls were, in general, placed in jars and hidden in 11 caves on the steep hillsides just north of the Dead Sea, in the region around the ancient settlement of Qumran, which was destroyed by the Romans about 2,000 years ago. To protect their religious and cultural heritage from the invaders, members of a sect called the Essenes hid their precious documents in the caves, often buried under a few feet of debris and bat guano to help foil looters.

The Temple Scroll is one of the largest (almost 25 feet long) and best-preserved of all the scrolls, even though its material is the thinnest of all of them (one-tenth of a millimeter, or roughly 1/250th of an inch thick). It also has the clearest, whitest writing surface of all the scrolls. These properties led MIT assistant professor of civil and environmental engineering and Department of Materials Science and Engineering faculty fellow in archaeological materials, Admir Masic, to wonder how the parchment was made.

The results of that study, carried out with former graduate student Roman Schuetz (now at Israel's Weizmann Institute of Science), MIT graduate student Janille Maragh, and two others, were published today in the journal Science Advances. They found that the parchment was processed in an unusual way, using a mixture of salts found in evaporites—the material left from the evaporation of brines—but one that was different from the typical composition found on other parchments.

"The Temple Scroll is probably the most beautiful and best preserved scroll," Masic says. "We had the privilege of studying fragments from the Israeli museum in Jerusalem called the Shrine of the Book," which was built specifically to house the Dead Sea Scrolls. One relatively large fragment from that scroll was the main subject of the new paper. The fragment, measuring about 2.5 cm (1 inch) across was investigated using a variety of specialized tools developed by researchers to map, in high resolution, the detailed chemical composition of relatively large objects under a microscope.

"We were able to perform large-area, submicron-scale, non-invasive characterization of the fragment," Masic says—an integrated approach that he and co-author of this paper James Weaver, from the Wyss Institute at Harvard University, have developed for the characterization of both biological and non-biological materials. "These methods allow us to maintain the materials of interest under more environmentally friendly conditions, while we collect hundreds of thousands of different elemental and chemical spectra across the surface of the sample, mapping out its compositional variability in extreme detail," Weaver says.

That fragment, which has escaped any treatment since its discovery that might have altered its properties, "allowed us to look deeply into its original composition, revealing the presence of some elements at completely unexpectedly high concentrations" Masic says.

The elements they discovered included sulfur, sodium, and calcium in different proportions, spread across the surface of the parchment.

Parchment is made from animal skins that have had all hair and fatty residues removed by soaking them in a lime solution (from the middle ages onwards) or through enzymatic and other treatments (in antiquity), scraping them clean, and then stretching them tight in a frame to dry. When dried, sometimes the surface was further prepared by rubbing with salts, as was apparently the case with the Temple Scroll.

The team has not yet been able to assess where the unusual combination of salts on the Temple Scroll's surface came from, Masic says. But it's clear that this unusual coating, laced with these salts, on which the text was written, helped to give this parchment its unusually bright white surface, and perhaps contributed to its state of preservation, he says. And the coating's elemental composition does not match that of the Dead Sea water itself, so it must have been from an evaporite deposit found somewhere else—whether nearby or far away, the researchers can't yet say.

The unique composition of that surface layer demonstrates that the production process for that parchment was significantly different from that of other scrolls in the region, Masic says: "This work exemplifies exactly what my lab is trying to do—to use modern analytical tools to uncover secrets of the ancient world".

Understanding the details of this ancient technology could help provide insights into the culture and society of that time and place, which played a central role in the history of both Judaism and Christianity. Among other things, an understanding of the parchment production and its chemistry could also help to identify forgeries of supposedly ancient writings.

According to Ira Rabin, one of the paper's co-authors from Hamburg University in Germany, "this study has far-reaching implications beyond the Dead Sea Scrolls. For example, it shows that at the dawn of parchment making in the Middle East, several techniques were in use, which is in stark contrast to the single technique used in the Middle Ages. The study also shows how to identify the initial treatments, thus providing historians and conservators with a new set of analytical tools for classification of the Dead Sea Scrolls and other ancient parchments."

This information could indeed be crucial in guiding the development of new preservation strategies for these ancient manuscripts. Unfortunately, it appears that much of the damage seen in the scrolls today arose not from their 2,000-plus years in the caves, but from efforts to soften the scrolls in order to unroll and read them immediately after their initial discovery, Masic says.

Adding to these existing concerns, the new data now clearly demonstrate that these unique mineral coatings are also highly hygroscopic—they readily absorb any moisture in the air, and then might quickly begin to degrade the underlying material. These new results thus further emphasize the need to store the parchments in a controlled humidity environment at all times. "There could be an unanticipated sensitivity to even small-scale changes in humidity," he says. "The point is that we now have evidence for the presence of salts that might accelerate their degradation. ... These are aspects of preservation that must be taken into account."

Explore further 21st century technology deciphers ancient Hebrew scroll

More information: "The Temple Scroll: Reconstructing an ancient manufacturing practice" Science Advances (2019). DOI: 10.1126/sciadv.aaw7494 , Journal information: Science Advances "The Temple Scroll: Reconstructing an ancient manufacturing practice"(2019). DOI: 10.1126/sciadv.aaw7494 , advances.sciencemag.org/content/5/9/eaaw7494