8: Oct 25 1953: Real Madrid 5, Barcelona 0 Real outwitted Barca to sign Alfredo Di Stefano, who went on to become one of the Madrid club's most legendary players, in one of Spain's most controversial transfer deals. Di Stefano made an instant impact. Two weeks after his move, he scored twice against Barca in a win that pointed Real towards their first Spanish title for 21 years.