Using a novel high-pressure precursor process, scientists from the Carnegie Institution for Science have synthesized an entirely new form of silicon.

Washington, D.C. — Silicon is the second most-abundant element in the earth’s crust. When purified, it takes on a diamond structure, which is essential to modern electronic devices—carbon is to biology as silicon is to technology. A team of Carnegie scientists led by Timothy Strobel has synthesized an entirely new form of silicon, one that promises even greater future applications. Their work is published in Nature Materials.

Although silicon is incredibly common in today’s technology, its so-called indirect band gap semiconducting properties prevent it from being considered for next-generation, high-efficiency applications such as light-emitting diodes, higher-performance transistors and certain photovoltaic devices.

Metallic substances conduct electrical current easily, whereas insulating (non-metallic) materials conduct no current at all. Semiconducting materials exhibit mid-range electrical conductivity. When semiconducting materials are subjected to an input of a specific energy, bound electrons can move to higher-energy, conducting states. The specific energy required to make this jump to the conducting state is defined as the “band gap.” While direct band gap materials can effectively absorb and emit light, indirect band gap materials, like diamond-structured silicon, cannot.

In order for silicon to be more attractive for use in new technology, its indirect band gap needed to be altered. Strobel and his team—Carnegie’s Duck Young Kim, Stevce Stefanoski and Oleksandr Kurakevych (now at Sorbonne) —were able to synthesize a new form of silicon with a quasi-direct band gap that falls within the desired range for solar absorption, something that has never before been achieved.

The silicon they created is a so-called allotrope, which means a different physical form of the same element, in the same way that diamonds and graphite are both forms of carbon. Unlike the conventional diamond structure, this new silicon allotrope consists of an interesting open framework, called a zeolite-type structure, which is comprised of channels with five-, six- and eight-membered silicon rings.

They created it using a novel high-pressure precursor process. First, a compound of silicon and sodium, Na4Si24, was formed under high-pressure conditions. Next, this compound was recovered to ambient pressure, and the sodium was completely removed by heating under vacuum. The resulting pure silicon allotrope, Si24, has the ideal band gap for solar energy conversion technology, and can absorb, and potentially emit, light far more effectively than conventional diamond-structured silicon. Si24 is stable at ambient pressure to at least 842 degrees Fahrenheit (450 degrees Celsius).

“High-pressure precursor synthesis represents an entirely new frontier in novel energy materials,” remarked Strobel. “Using the unique tool of high pressure, we can access novel structures with real potential to solve standing materials challenges. Here we demonstrate previously unknown properties for silicon, but our methodology is readily extendible to entirely different classes of materials. These new structures remain stable at atmospheric pressure, so larger-volume scaling strategies may be entirely possible.”

“This is an excellent example of experimental and theoretical collaboration,” said Kim. “Advanced electronic structure theory and experiment have converged to deliver a real material with exciting prospects. We believe that high-pressure research can be used to address current energy challenges, and we are now extending this work to different materials with equally exciting properties.”

This work was supported DARPA and Energy Frontier Research in Extreme Environments (EFree), an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science.

Publication: Duck Young Kim, et al., “Synthesis of an open-framework allotrope of ​silicon,” Nature Materials (2014); doi:10.1038/nmat4140

Image: Timothy Strobel