Russia’s Orthodox church has announced it will cut ties with the head of the church in Constantinople in a bitter row over plans to recognise a rival branch in the pro-Western portion of Ukraine.

The Russian renunciation of ties came as Bartholomew I, the Archbishop of Constantinople and de facto head of the Orthodox church’s 300 million Christians, looked set to approve the new Ukrainian church in a serious blow to the authority and prestige of Moscow.

Ahead of the decision, Patriarch Bartholomew sent two representatives to Ukraine this month, sparking fury in Russia where the Russian president, Vladimir Putin, continues to see Ukraine as part of a greater Russia.

In an apparent pre-emptive move against Bartholmew’s impending recognition, the Russian Orthodox Church said on Friday it would no longer conduct joint services with the Patriarchate of Constantinople and its own Patriarch, Kirill, will stop mentioning Bartholomew I in his prayers.

"Essentially this is a breakdown of relations. To take an example from secular life, the decision is roughly equivalent to cutting diplomatic ties," the Russian Church's Metropolitan Hilarion was quoted by RIA news agency as saying.