A woman who exploited lonely and vulnerable men by promising to introduce them to their "perfect match" has been ordered to pay back more than $342,000 in compensation.

Hollie Veall pressured clients of the introductions agency TLC - also known as True Love Corp - to part with tens of thousands of dollars to meet women who, in many cases, didn't exist.

Ms Veall persuaded one man, a bus driver, to hand over a total of $87,000 by emotionally manipulating him, saying: "How would you feel if all your life you had no one special in it? When you pass away, no one will remember you".

Another man, a divorced grazier, paid TLC a total of $190,000 after Ms Veall told him membership of the agency's "marriage file" would "guarantee him a wife".

The Director-General of the Department of Services, Technology and Administration took action in the NSW Supreme Court against Ms Veall, the long-time director of TLC, Zivko Dimitrijevski and his wife Helen Dimitrijevski.