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One in five Coalition MPs have links with private firms who could profit from the Government’s NHS reforms, a damning dossier will reveal on Tuesday.

Prime Minister David Cameron, former Health Secretary Andrew Lansley and his successor Jeremy Hunt are among 64 Tory MPs named in a study by the Unite union.

Deputy PM Nick Clegg and Business Secretary Vince Cable are among seven Liberal Democrats on the list.

All 71 MPs named in the dossier voted in favour of the Government’s controversial Health and Social Care Act in 2012, which opened up the NHS to more private firms.

It comes ahead of Friday’s crunch vote on Labour frontbencher Clive Efford’s Private Members’ Bill, when MPs will decide whether to scrap key sections of the Act.

Unite general secretary Len McCluskey raged: “This dossier of disgrace exposes the corruption at the heart of our Government’s sinister health reforms.”

He added: “The Government’s real plan is the complete and irreversible privatisation of our NHS.”

Many of the MPs named in the document have directly received donations from business leaders or firms with links to the private health industry.

There is no suggestion any of the politicians or donors acted illegally.

The Conservative Party stressed tonight that all donations are reported to the Electoral Commission in line with electoral law.

But critics said the dossier shines a bright light on the close ties between members of the ­Coalition and the private health industry.

Mr McCluskey said: “The sheer scale of the conflict of interest is staggering.

"But it is the subsequent betrayal and privatisation of our NHS, driven by the monstrous Health and Social Care Act, that has made this a genuine scandal for our democracy.”

The dossier shows Mr Lansley, the chief architect of the Coalition’s NHS reforms, accepted a £21,000 donation in November 2009 from John Nash, the former chairman of Care UK.

Two other Tory MPs received donations from Mr Nash’s wife Caroline.

Mr Hunt, who took over as Health Secretary when Mr Lansley was sacked in September 2012, received more than £20,000 from hedge fund baron Andrew Law, a major investor in health care firms.

Other Cabinet Ministers to have received donations include Leader of the Commons William Hague, who accepted £20,000 from MMC Ventures, the part-owner of The Practice plc which runs 60 GP surgeries.

And Culture ­Secretary Sajid Javid received £11,000 from Moundsley Healthcare Ltd.

The Prime Minister is named in the dossier after handing a life peerage to nursing and care home tycoon Dolar Popat, who has given the Tories more than £200,000 in donations.

Work and Pensions Secretary Iain Duncan Smith has share options in hygiene tech firm Byotrol, which sells products to the NHS.

Foreign Secretary Philip Hammond is named because his former firm Castlemead is a health care and nursing home developer.

Andy Burnham, Labour’s Shadow Health Secretary, said of the Tories: “They were bankrolled by private health in Opposition as they drew up secret plans to put market forces at the heart of the NHS.

"And once in Government, MPs and peers with links to private health voted it through without a mandate from the public.”

For the Lib Dems, the dossier says party leader Mr Clegg received a £5,000 donation to his constituency office from Alpha Medical Consultancy.

And Vince Cable was given £2,000 by Chartwell Care Services, which is owned by Chartwell Health & Care plc.

Tonight a Conservative spokesman hit back, and said: “Here in the ­Conservative Party, donations don’t buy our leader, our candidates or our ­policies. If only the same could be said of Unite and the Labour Party.

“The most important thing with NHS care is that it is high quality and free at the point of delivery.”

A Lib Dem spokesman said his party had “stopped Conservative privatisation plans and reversed Labour’s special favours to private health companies”.

He added: “We have already committed to spending at least £1billion extra on health and care in each year of the next Parliament.”

Full list of MPs with links to private healthcare firms

1. David Cameron – Prime Minister

Handed a peerage to nursing and care home tycoon Dolar Popat, who has given the Tories more than £200,000 in donations.

2. Andrew Lansley - Former Health Secretary & architect of privatisation

Received a £21,000 donation in Nov 2009 from John Nash, the former chairman of Care UK.

3. Harriet Baldwin – Tory whip

Former executive at JP Morgan, a major player in private healthcare.

4. Greg Barker – former Energy Minister

Held shares in Quester VCT 5 plc ,a venture capital firm with multiple investments in healthcare companies.

5. Henry Bellingham

Former director of Lansdowne Advisory Ltd, which has shares in private healthcare company Circle.

6. Jake Berry

Has registered interests in legal firm Squire Patton Boggs, which workd with multiple NHS trusts on PFI and PPP programs.

7. Graham Brady

Former advisor to PA Consulting, a management consultancy company which has worked with the NHS’s new Clinical Commissioning Groups.

8. Simon Burns – former Health Minister

Attended an oncology conference paid for by Aventis Pharma - a five-day trip to the US funded by a leading drug firm.

9. Nick de Bois

Was the majority shareholder in Rapier Design Group, an events management company heavily involved with the private medical and pharmaceutical industries.

10. Steve Brine

Received almost £15,000 in donations from James Lupton, the chairman of investment bankers, Greenhill Europe which has a global network of corporate relationships in the healthcare sector.

11. Aidan Burley

Received six bottles of wine from Hitachi consultants for a speech in 2011. Hitachi Consulting UK built an online ‘portal’ for NHS commissioners to help them monitor performance.

12. Damian Collins

Spent almost a decade working for marketing agency M&C Saatchi, whose clients include PPP healthcare, AXA insurance, Astrazeneca, Pfizer and Merck

13. David Davis – former shadow home secretary

Received a payment of £4,250 for a six-hour speaking engagement for private health insurance company Aviva.

14. Jonathan Djanogly

Received £1,900 from Huntleigh Healthcare Ltd, which manufactures medical and orthopaedic equipment and instruments.

15. Richard Drax

Received £14,000 in a series of donations from Derek Luckhurst, chief executive and owner of care home group Agincare.

16. Iain Duncan-Smith – Work and Pensions Secretary

Has shares in hygiene technology company Byotrol plc, which sells products to the NHS.

17. Philip Dunne

Was a non-executive director for investment firm Baronsmead VCT 4 plc, which had multiple investments in private healthcare companies.

18. Michael Fallon – Defence Secretary

Former director of Attendo AB, - a Swedish private health company.

19. Mark Field

Was a board advisor to Ellwood and Atfield; a recruitment firm which recruit for NHS positions and private healthcare.

20. Liam Fox – former Defence Secretary

Received £5,000 from investment company IPGL Ltd, who purchased healthcare pharma company Cyprotex.

21. George Freeman

Has shares in Hill House Assets Ltd, formally private health firm 4D Biomedical Ltd.

22. Mike Freer

Provided marketing advice to Care Matters, a financial planning company for care homes.

23. Richard Fuller

Worked for L.E.K consulting, which has six ‘partners’ in European healthcare.

24. Richard Graham

Received £3,000 from asset manager Crispin Odey, a major investor in Circle.

25. William Hague – Leader of the Commons

Received a £20,000 donation from MMC Ventures, which parts owns The Practice plc which runs 60 GP surgeries.

26. Philip Hammond – Foreign Secretary

Beneficiary of a trust which owns a controlling interest in healthcare and nursing home developer Castlemead Ltd.

27. Mark Harper

Received £5,000 from asset manager Crispin Odey, a major investor in Circle.

28. Nick Herbert

Received £15,000 in donations from Caroline Nash, wife of former Care UK chairman John Nash.

29. Jeremy Hunt – Health Secretary

Received £32,920 from hedge fund baron Andrew Law, a major investor in healthcare firms.

30. Margot James

Had a key role at marketing giant WPP Group, which had a long list of healthcare clients.

31. Sajid Javid – Culture Secretary

Received £11,000 from Moundsley Healthcare Ltd last year.

32. Jo Johnson – Downing Street policy adviser

Received £6,000 from asset manager Crispin Odey, a major investor in Circle.

33. Kwarsi Kwateng

Worked as an analyst for for Crispin Odey’s hedge fund Odey Asset Management.

34. Mark Lancaster

Former adviser to property venture capital firm Company Palmer Capital Partners Ltd, a funder of Danescroft Commercial Developments, which has worked in the healthcare sector.

35. Dr Phillip Lee

Has worked as a freelance or Medical Solutions Ltd, which provided medical cover for events.

36. Oliver Letwin – former shadow chancellor

Was a non-executive director of N.M. Rothschild Corporate Finance Ltd, which invests heavily in healthcare.

37. Peter Lilley

Non-Executive director of management software firm Idox plc, which provides services to the NHS Health Libraries Group and NHS Education for Scotland.

38. Tim Loughton

Received £350 for training sessions with Cumberlege Connections, a political networking firm that works “extensively” with the pharmaceutical industry.

39. Mary Macleod

Was a senior executive at Andersen Consulting/Accenture, which has profited from big PFI deals.

40. Francis Maude – Cabinet Office Secretary

Was a director of PR firm Huntsworth plc, which was part of lobbying group Healthcare Communications Association.

41. Maria Miller – former Culture Secretary

Former director of Grey’s Advertising Ltd, an advertising and brand company which worked extensively with clients in the healthcare sector.

42. Andrew Mitchell – former International Development Secretary

Was a strategy adviser to global management firm Accenture, which has worked extensively with private healthcare companies and the NHS.

43. Penny Mordaunt – Communities Minister

Worked for lobbying firm Hanover, where she had a range of healthcare clients.

44. Brooks Newmark – former Charities Minister

Partner in the Allele Fund, which invests in healthcare startups.

45. Jesse Norman

Received £5,000 from asset manager Crispin Odey, a major investor in Circle.

46. Stephen O’Brien

Received payments totalling £40,000 from Julian Schild, whose family made £184million in 2006 by selling hospital bed-makers Huntleigh Technology.

47. George Osborne - Chancellor

Received donation through Conservative Campaign Headquarters from Julian Schild – see above.

48. Priti Patel – Treasury Minister

Worked for lobbying firm Weber Shandwick, which does PR for big healthcare and pharmaceutical firms.

49. John Redwood – former Cabinet Minister

Advised the private equity company which runs Pharmacy2u, the UK’s largest dedicated internet and mail order pharmacy.

50. Jacob Rees-Mogg

Partner of Somerset Capital Management LLP, which has healthcare investor Redwood Emerging Markets Dividend Income Fund as a client.

51. Sir Malcolm Rifkind – former Foreign Secretary

Chairman of advisory board at L.E.K. Consulting LLP, which helps private healthcare firms identify “new business development” and “opportunities with the Government”.

52. Amber Rudd – Energy Minister

Received £3,000 from hedge fund baron Andrew Law, a major investor in healthcare firms.

53. David Ruffley

Received £10,000 in donations from Caroline Nash, wife of former Care UK chairman John Nash.

54. Mark Simmonds – former Foreign Minister

Was paid £50,000 a year as a “strategic adviser” to Circle Health.

55. Chris Skidmore

Received £3,500 for speeches to STAC Consultancy, which specialises in the launch of pharmaceutical products.

56. Julian Smith

Received a £2,500 donation from Principle Healthcare Ltd in September 2014.

57. Nicholas Soames

Received £2,000 from asset manager Crispin Odey, a major investor in Circle.

58. John Stanley

Consultant on financial services to FIL Investment Management Ltd, which invests in healthcare.

59. Andrew Tyrie - select committee chairman

Attended the Ryder Cup as Secretary of the Parliamentary Golf Society, with travel and accommodation paid for by U.S. healthcare services company Humana Europe.

60. Robin Walker:

His office received a £2,000 donation from Redwood Care Homes, which owns multiple care homes.

61. David Willetts – former Universities Minister

Has shares in Sensortec, a company that owns Vantix which was working on a contract for a new product to detect MRSI.

62. Rob Wilson

Had registered shares in Vital Imaging, a private screening company.

63. Tim Yeo

Also attended the 2008 Ryder Cup, courtesy of Humana Europe.

64. Nadhim Zahawi

Non-executive director of recruitment company SThree, which specialises in the Ppharmaceutical and biotechnology sector.

65. Menzies Campbell – former leader

Non-executive director of Scottish American Investment Company plc, which took over one of the care homes when Southern Cross collapsed.

66. Vince Cable – Business Secretary

Received a donation of £2,000 from Chartwell Care Services, which is 100% owned by Chartwell Health & Care PLC. It also owns Chartwell Private Hospitals plc, which provide day case surgery to NHS patients.

67. Nick Clegg – Deputy Prime Minister

Received a donation to his constituency office for £5,000 from Alpha Medical Consultancy.

68. Simon Hughes – Justice Minister

Received £60,000 donation to his constituency party from the founder of Alpha Hospitals, a private hospital firm.

69. Stephen Lloyd

MP for Eastbourne. Received £544.92 aggregated over time for office equipment from Platon Medical Ltd - who provides Ear, Nose and throat devices.

70. Robert Smith

Has shares in pharmaceutical giant GlaxoSmithKline.

71. Jo Swinson – Business Minister

Received a donation of £2,000 September 2013 from private optician firm, Peter Ivins Eye Care.