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To achieve significant efficiency and low roll-off in thermally activated delayed fluorescence (TADF) material organic light-emitting diodes (OLEDs), it is essential to choose a host that has suitable high triplet energy (T) and bipolar character to boost the TADF characteristics as a dopant and avoid exciton annihilation. Herein, we present the effect of different host materials on the efficiency of organic light-emitting diodes (OLEDs) based on bis[4-(3,6 dimethoxycarbazole)phenyl]sulfone (DMOC-DPS) deep-blue emitter. The devices with 10 wt.% of an emitter in different electron types of host bis[2-(diphenylphosphino) phenyl] ether oxide (DPEPO), and hole types of host 1,3-bis(-carbazolyl)benzene (mCP), were fabricated to study the effect on device performance. The results show that an external quantum efficiency (EQE) of 4% and maximum current efficiency (ƞ) up to 5.77 cd/A with high luminescence (l) 8185 cd/min DPEPO was achieved, compared to 2.63% EQE, ƞ4.12 cd/A with l5338 cd/min mCP in a very simple device structure. As a remarkable result, the roll-off is suppressed at 1000 cd/m, and for maximum brightness, the roll-off is less than 50%. Further general applications are discussed. View Full-Text