RJSONIO from Omegahat is another package which provides facilities for reading and writing data in JSON format.

rjson does not use S4/S3 methods and so is not readily extensible, but still useful. Unfortunately, it does not used vectorized operations and so is too slow for non-trivial data. Similarly, for reading JSON data into R, it is somewhat slow and so does not scale to large data, should this be an issue.

Update (new Package 2013-12-03):