Felice Macera

‘Hidden’ phases of matter revealed through laser pulses

Hidden states of matter activated by light pulses are opening the door to new materials with hugely useful new properties.

Most people think of water as existing in only one of three phases — Solid ice, liquid water, or gas vapour. But matter can exist in many different phases — ice, for example, has more than ten known phases, or ways that its atoms can be spatially arranged.

The widespread use of piezoelectric materials, such as microphones and ultrasound, is possible thanks to a fundamental understanding of how external forces like pressure, temperature, or electricity, can lead to phase transitions that imbue materials with new properties.

Now a new study has found that a metal oxide has a ‘hidden’ phase — one which gives the material new, ferroelectric properties — including the ability to separate positive and negative charges when it is activated by extremely fast pulses of light.

MIT researchers Keith A. Nelson, Xian Li, and Edoardo Baldini, spearheaded the research in collaboration with Andrew M. Rappe and Penn graduate students Tian Qiu and Jiahao Zhang. Their findings were published in the journal Science.

The findings open the door to creating materials, in which properties can be turned off in a trillionth of a second with the flick of a switch with far greater control than currently possible.

In addition to changing electric potential, this approach could be used to change other aspects of existing materials — turning an insulator into a metal or flipping its magnetic polarity, for example.

As Rappe says: “It’s opening a new horizon for rapid functional material reconfiguration.”

The group studied strontium titanate, — a paraelectric material used in optical instruments, capacitors, and resistors — which has a symmetric and nonpolar crystal structure. This structure can be “pushed” into a phase with a polar, tetragonal structure with a pair of oppositely charged ions along its long axis.

Nelson and Rappe’s previous collaboration provided the theoretical basis for this new study, which relied on Nelson’s experience using light to induce phase transitions in solid materials along with Rappe’s knowledge in developing atomic-level computer models.

A new study reveals a “hidden” phase of strontium titanate. On the left, extremely fast pulses of light excites atoms within the crystal structure (red arrows), which shifts the material into a new, ferroelectric phase. Vibrations of other atoms then work to stabilize the hidden phase (right panels). (Felice Macera)

Rappe says: “[Nelson is] the experimentalist, and we’re the theorists. He can report what he thinks is happening based on spectra, but the interpretation is speculative until we provide a strong physical understanding of what happened.”

With an eye on recent improvements in technology and additional knowledge gained from working with terahertz frequencies, the two chemists set out to see if their theory — now more than a decade old — held true.

The challenge facing Rappe was to complement Nelson’s experiments with an accurate computer-generated version of strontium titanate — one that tracks every single atom that responds to light in the same manner as the material being tested in the lab.

The team discovered that when strontium titanate is excited with light, the ions are pulled in different directions — positively charged ions moving in one direction and negatively charged ions in the other. Then, rather than the ions immediately falling back into place — the way a pendulum would after it’s been pushed in a so-called steady-state arrangement — vibrational movements induced in the other atoms prevent the ions from swinging back immediately.

It’s as if the pendulum, at the moment that it reaches the maximum height of its oscillation, is diverted slightly off course where a small notch holds it in place — away from its initial position.

Thanks to their strong history of collaboration, Nelson and Rappe were able to go back and forth from the theoretical simulations to the experiments, and vice versa, until they found experimental evidence that showed that their theory held true.

Nelson says: “It’s been a really awesome collaboration. And it illustrates how ideas can simmer and then return in full force after more than 10 years.”

The two chemists will now collaborate with engineers on future applications-driven research — including creating new materials that have hidden phases, changing light-pulse protocols to create longer-lasting phases, and seeing how this approach works for nanomaterials. For now, both researchers are excited about their results and where this fundamental breakthrough could lead to in the future.

Rappe enthuses: “It’s the dream of every scientist: To hatch an idea together with a friend, to map out the consequence of that idea, then to have a chance to translate it into something in the lab, it’s extremely gratifying. It makes us think we’re on the right track towards the future.”

Original research: https://science.sciencemag.org/content/364/6445/1079