By using the top electrode as the catalyst that turns plain silicon into valuable black silicon, scientists from Rice University have developed a way to simplify the production of solar cells.

The Rice lab of chemist Andrew Barron disclosed the research in the American Chemical Society journal ACS Applied Materials and Interfaces.

Black silicon is silicon with a highly textured surface of nanoscale spikes or pores that are smaller than the wavelength of light. The texture allows the efficient collection of light from any angle, at any time of day. Barron and his team have been fine-tuning the creation of black silicon for some time, but an advance in the manufacturing technique should push it closer to commercialization, he said.

Barron noted the new work led by Rice postdoctoral researcher Yen-Tien Lu has two major attractions. “One, removing steps from the process is always good,” he said. “Two, this is the first time in which metallization is a catalyst for a reaction that occurs several millimeters away.”

Barron said the metal layer used as a top electrode is usually applied last in solar cell manufacturing. The new method known as contact-assisted chemical etching applies the set of thin gold lines that serve as the electrode earlier in the process, which also eliminates the need to remove used catalyst particles.

The researchers discovered that etching in a chemical bath takes place a set distance from the lines. That distance, Barron said, appears to be connected to the silicon’s semiconducting properties.

“Yen-Tien was doing the reaction with gold top contacts, adding silver or gold catalyst and getting these beautiful pictures,” he said. “And I said, ‘OK, fine. Now let’s do it without the catalysts.’ Suddenly, we got black silicon — but it was etching only a certain distance away from the contact. And no matter what we did, there was always that distance.

“It told us the electrochemical reaction is occurring at the metal contact and at the silicon that’s a certain distance away,” Barron said. “The distance is dependent upon the charge-carrying capacity, the conductivity, of the silicon. At some point, the conductivity isn’t sufficient for the charge to carry any further.”

Barron said an extremely thin layer of gold atop titanium, which bonds well with both gold and silicon, should be an effective electrode that also serves for catalysis. “The trick is to etch the valleys deep enough to eliminate the reflection of sunlight while not going so deep that you cause a short circuit in the cell,” he said.

He said the electrode’s ability to act as a catalyst suggests other electronic manufacturing processes may benefit from a bit of shuffling.

“Metal contacts are normally put down last,” Barron said. “It begs the question for a lot of processes of whether to put the contact down earlier and use it to do the chemistry for the rest of the process.”

The research was supported by the Robert A. Welch Foundation, the Welsh Government Sêr Cymru Program and Natcore Technology.

Barron is the Charles W. Duncan Jr.-Welch Professor of Chemistry and a professor of materials science and nanoengineering at Rice and the Sêr Cymru Chair of Low Carbon Energy and Environment at Swansea University.

Publication: Yen-Tien Lu and Andrew R Barron, “In-situ fabrication of a self-aligned selective emitter silicon solar cell using the gold top contacts to facilitate the synthesis of a nanostructured black silicon anti-reflective layer instead of an external metal nanoparticle catalyst,” ACS Appl. Mater. Interfaces, 2015; DOI: 10.1021/acsami.5b01008

Images: Courtesy of the Barron Group