I found a very good explanation, on allpar, as to why our Hemi engines have 16 spark plugs. Here it is:



"Each cylinder has an ignition coil pack over one spark plug, and a regular plug wire connected to the other spark plug. Further, the coil pack also has a plug wire attached to it that extends to the opposite cylinder bank. Each cylinder shares a coil pack with another cylinder. Each of the two plugs on a given cylinder is fired by a separate coil. One plug has a coil directly attached, and the other is fired via an ignition wire connected to a coil located on another cylinder on the opposite bank. The extra plug fires during the power stroke to more fully burn the hydrocarbons. The second ignition allows additional power in the down stroke while lowering the need for restrictive catalyst plates in the converter.



In the 1980s Japanese manufacturers reduced unburned hydrocarbons by placing spark plugs either in the exhaust pipe (which fired with every piston ignition) or in the exhaust manifold (which fired each time their corresponding cylinder fired). Chrysler morphed this idea to include dual fired plugs on each cylinder, which allows the firing to take place closer to top dead center, and then again when the piston is on the back side of the power stroke. This also reduces NOx and ozone. Full combustion results in heat, water, and carbon dioxide. NOx emissions are only significant during incomplete or partial combustion, due to the lack of available oxygen, high temperatures, and various chemical reactions. That's why catalytic converters have been standard on cars for the past 3 decades. The extra set of spark plugs on the HEMI, and on previous engines, are designed to reduce emissions before a catalyst is needed. They add some horsepower, but not very much."