Graphene ribbons that are only a few atoms wide, so-called graphene nanoribbons, have special electrical properties that make them promising candidates for the nanoelectronics of the future: while graphene – a one atom thin, honeycomb-shaped carbon layer – is a conductive material, it can become a semiconductor in the form of nanoribbons. This means that it has a sufficiently large energy or band gap in which no electron states can exist: it can be turned on and off – and thus may become a key component of nanotransistors.

The smallest details in the atomic structure of these graphene bands, however, have massive effects on the size of the energy gap and thus on how well-suited nanoribbons are as components of transistors. On the one hand, the gap depends on the width of the graphene ribbons, while on the other hand it depends on the structure of the edges. Since graphene consists of equilateral carbon hexagons, the border may have a zigzag or a so-called armchair shape, depending on the orientation of the ribbons. While bands with a zigzag edge behave like metals, i.e. they are conductive, they become semiconductors with the armchair edge.

This poses a major challenge for the production of nanoribbons: if the ribbons are cut from a layer of graphene or made by cutting carbon nanotubes, the edges may be irregular and thus the graphene ribbons may not exhibit the desired electrical properties.