Missing student Libby Squire was captured on CCTV walking towards a nightclub in Hull on the night she disappeared.

The 21-year-old was filmed near The Welly Club a few minutes after she was turned away by doormen.

The philosophy student appears unsteady on her feet as she walks along the slippery path that had been covered in snow earlier on the evening of 31 January, when she went missing.

"This footage shows that she was dressed all in black and seems to be wearing lighter coloured trainers or boots," Lukasz Rybus told Mail Online. The property agent who owns the footage, added: "I just hope that this footage helps jog someone's memory, if it helps someone remember seeing her, that can only be a positive thing."

Humberside Police had earlier said that Ms Squire took a taxi from the nightclub and arrived near her home at around 11.29pm.

Libby Squire search: disappearance of 21-year-old university student Show all 18 1 /18 Libby Squire search: disappearance of 21-year-old university student Libby Squire search: disappearance of 21-year-old university student Police officers began searching after Hull university student, Libby Squire, went missing after a night out Getty Images Libby Squire search: disappearance of 21-year-old university student The 21-year-old was last seen on Thursday 31 January, 2019 PA Libby Squire search: disappearance of 21-year-old university student Officers have said Ms Squire was dropped off in a taxi near her home on Wellesley Avenue at 11.29pm on Thursday and was seen 10 minutes later on CCTV near a bench on Beverley Road, where a motorist stopped to offer her help PA Libby Squire search: disappearance of 21-year-old university student Libby's parents Lisa and Russ Ms Squire’s family said her disappearance is completely out of character and described her as a “very thoughtful and caring young woman who puts others before herself” PA Libby Squire search: disappearance of 21-year-old university student More than 200 volunteers joined 70 police and the Hull Coastguard Rescue Team searching the city for her PA Libby Squire search: disappearance of 21-year-old university student Welly Club on Beverley Road PA Libby Squire search: disappearance of 21-year-old university student Friends have said the student did not have her phone on her during the night PA Libby Squire search: disappearance of 21-year-old university student Her parents Lisa and Russ issued a statement thanking everyone who had helped in the search for their daughter, saying they had been “overwhelmed with people’s kindness and support”. They said: “Growing up, Libby was a really happy child, and she is extremely close to her family and her siblings.” PA Libby Squire search: disappearance of 21-year-old university student Officers urged people living in the area to check their gardens and outbuildings in case she had taken shelter PA Libby Squire search: disappearance of 21-year-old university student President of University of Hull Students' Union Osaro Otabo (left) and Vice-Chancellor of the university Professor Susan Lea as they address students and staff gathered in solidarity and support of student Libby PA Libby Squire search: disappearance of 21-year-old university student Police search in Newland near Hull PA Libby Squire search: disappearance of 21-year-old university student A police officer with a dog conducts a search on Wellesley Avenue PA Libby Squire search: disappearance of 21-year-old university student Police search the frozen Oak Road Pond Getty Images Libby Squire search: disappearance of 21-year-old university student Police search on the Beverley and Barmston Drain PA Libby Squire search: disappearance of 21-year-old university student Staff and students gather at the University of Hull in solidarity and support of student Libby Squire, who has been missing from her home in the city since early on Friday. PRESS ASSOCIATION Photo. Picture date: Tuesday February 5, 2019. See PA story POLICE Hull. Photo credit should read: Danny Lawson/PA Wire Danny Lawson PA Libby Squire search: disappearance of 21-year-old university student Police officers search drains near to the home of missing 21-year-old student Libby Squire Getty Images Libby Squire search: disappearance of 21-year-old university student Police search Oak Road Pond PA Libby Squire search: disappearance of 21-year-old university student Police search for missing 21-year-old student Libby Squire, on the Beverley and Barmston Drain PA

She was then seen near a bench around 10 minutes later, when a motorist stopped and offered to help her.

The student is believed to have been near the bench until shortly after midnight.

A spokesperson for Humberside Police said both the taxi driver and motorist have been spoken to and are not suspects.

Officers had earlier arrested Pawel Relowicz on suspicion of abducting Ms Squire.

CCTV footage shows moments before Libby Squire was last seen

Detectives with Humberside Police were granted until 9pm on Sunday to question the 24-year-old as they continued to search his home in Hull.

They later announced that Mr Relowicz had been charged with three counts of burglary, voyerism and outraging public decency relating to separate offences reported between December 2017 and 19 January this year.

Speaking through a Polish interpreter, he pleaded not guilty to all charges at Hull Magistrates Court and was remanded in custody earlier this week.