SF 6 , the most potent greenhouse gas in existence, was banned for all applications in the EU in 2014 – except in the electricity industry. The reason for the exemption, writes Nicholas Ottersbach, researcher at German cleantech startup Nuventura, was that there was no viable alternative. But according to Ottersbach that is no longer the case. He calls on EU policymakers to ban SF 6 , in the electricity industry when the relevant EU legislation is reviewed in 2020.

In 2014 the European Union (EU) reinforced a 2006 F-Gas regulation, aiming to strengthen measures to contain the polluting emissions of fluorinated gases (F-gases) (EU Commission, 2015). F-gases are a family of man-made gases with the strongest greenhouse effect. Of all the F-gases, SF 6 (the focus of this paper), is the most potent.

This regulation’s aim is to bring down the EU’s F-gas emissions by two-thirds from 2014 levels by 2030 as part of the ultimate objective of cutting overall greenhouse gas (GHG) emissions by at least 80% by 2050 against 1990 levels (Biasse, 2014). However, the new restrictions on the use of SF 6 did not affect its largest user, the electrical power equipment industry. The EU regulation mentions phase-out dates for F-gases used in many applications, depending on their global warming potential (GWP) yet it does not mention SF 6 in switchgear meaning, in effect, that there are no restrictions (Biasse, 2014).

SF 6 is a long-lived, highly potent greenhouse gas. It is manmade and combines excellent electrical properties with chemical stability and low toxicity.

Having said this, the regulation does have a provision for reviewing the situation in 2020 which should provide fresh impetus for policy makers, and interested actors, to give this gas the serious attention it deserves. This is especially pertinent as large parts of EU regulations are often followed by developing countries’ laws, to get access to the EU market.

What is SF 6 ? and how is it used?

SF 6 is a long-lived, highly potent greenhouse gas. It is manmade and combines excellent electrical properties with chemical stability and low toxicity. Moreover, It’s non-flammable and low in cost. These characteristics have led to its widespread and enthusiastic adoption by the electrical industry, which uses approximately 80% of all SF 6 produced (Powell, 2002: 6).

Within the electrical industry SF 6 is used as an insulating medium for medium (MV) and high (HV) voltage electrical switchgear. A switchgear is the combination of electrical disconnect switches, fuses or circuit breakers used to control, protect and isolate sections of electrical grids. Low-voltage (LV) switchgear are used for controlling electrical circuits within buildings, medium voltage (MV) switchgear for controlling the electrical grids within cities and towns, and high voltage (HV) switchgear for grids that span a greater geographical area such as countries and regions.

Is SF 6 a danger to human health?

In its normal and inert form SF 6 is relatively harmless to humans. However, when exposed to electrical discharges through everyday usage within SF 6 -filled equipment, highly toxic by-products are produced that pose a serious threat to those in close proximity to the switchgear (ICF Consulting, 2002: 1).

These byproducts include, among other things, disulfur decafluoride (S 2 F 10 ) which is a highly toxic gas (Blackburn 2015: 2). It has been referred to by the US Environmental Protection Agency (EPA) as “the byproduct of greatest concern due to its relatively high toxicity.” (ICF Consulting, 2002: 2)

Unlike gases such as CO 2 , SF 6 has no natural sink, origin or effective disposal method, making its accumulation in the atmosphere virtually irreversible

S 2 F 10 ’s toxicity is on a par with phosgene, the infamous chemical warfare pulmonary agent used during the First World War (Blackburn, 2015: 2). Its weaponization was also considered during the Second World War due to its toxic nature, as it provided little warning of exposure to the victim (Blackburn, 2015: 2).

The presence of such by-products is of real concern due to the documented fact of leakage, as well as uncontrolled releases or discharges that occur during routine development, testing, commissioning, maintenance and repair, and decommissioning of SF 6 -filled equipment. For companies using SF 6 these dangers represent, at best, increased handling costs due to required safety measures, and at worst a real risk to human life. They also lead to legitimate concerns over the health and welfare of utility employees as well as the communities that host switchgear stations.

How environmentally damaging is it?

With a GWP of around 22,800 over a 100-year time horizon, SF 6 is the most potent greenhouse gas regulated under the Kyoto Protocol (Rigby et al, 2010: 10305). Its GWP of 22,800 means that it is 22,800 times more effective at trapping infrared radiation (i.e., creating the greenhouse effect) than an equivalent amount of carbon dioxide over a 100-year period (Blackburn, 2015: 5).

Moreover, it is widely believed to have an atmospheric lifetime of 3,200 years (Diggelmann et al, 2016: 70), although recent research suggests shorter lifetimes. Some say 850 years (with a range from 580 to 1,400 years) (Ray et al, 2017: 4626) while other research suggesting closer to 1,278 years (with a range of 1,120 to 1,475) (Kovács, 2017: 883). In any case, it is clearly an extremely long-lived gas, and poses a serious problem through its contribution to the immediate threat of global warming.

As well as having an extremely long lifetime, unlike gases such as CO 2 , it has no natural sink, origin or effective disposal method, making its accumulation in the atmosphere virtually irreversible (Blackburn, 2015: 5). Without disposal methods that completely destroy SF 6 , it can be expected that all of the SF 6 that has been or will be produced will eventually end up in the atmosphere (Dervos and Vassiliou, 2000: 138).

Studies also show that atmospheric concentrations of SF 6 have increased by more than a factor of 10 since measurements began in 1973 (Rigby et al, 2010: 10305). They also found that global emissions are higher now than ever, and have increased by almost 50% between 2000 and 2010 (Rigby et al, 2010: 10305).

Global annual SF 6 production is currently around 8,000 tonnes (Damsky, 2016: 1). Furthermore, based on atmospheric data, global SF 6 emissions in 2012 were 8,100 tonnes (Dunse et al, 2015: 20) essentially creating a production-emission parity. These emissions are the equivalent of the annual greenhouse footprint of approximately 40 million cars (EPA, 2017). Despite these environmental consequences, SF 6 ’s use in the electrical industry is forecast to grow by around 50%, from 2005 levels, by 2030 (Rhiemeier et al, 2010: 29). .

Has the environmental impact even been underestimated?

Although SF 6 ’s GWP of 22,800 firmly establishes it as the most dangerous known greenhouse gas, the number may be unrepresentative of its true environmental threat. The IPCC, for example, gives SF 6 a higher GWP of 23,500 (Myhre & Shindell, et al. 2013: 733). Moreover since GWP accounts only for 100 years of the gas’ atmospheric lifetime, the real impact is much higher. If one assumes a 500-year time horizon, it grows to 32,600 (IPCC, 2005) and, even then, remains only a fraction of its true impact on global warming. This begs the question as to whether the gravity of SF 6 ’s impact on global warming has really been understood? And whether we can continue to rationalize its use in the electrical industry?

Considering that the measurement approaches on which emissions regulation is based are fundamentally erroneous, how can we be certain that the SF 6- reduction measures taken so far by the EU, and by extension the electrical industry, have been effective?

Furthermore, research shows that up to 80% of SF 6 emissions are not reported at all (Levin et al. 2010: 2655). A reason for this is that Asian countries, such as China, India and South Korea, who are driving the increase in emissions, do not report their SF 6 emissions to the United Nations Framework Convention on Climate Change (UNFCCC) (Rigby, 2010: 10316). Another reason is that developed countries that do report emissions to the UNFCCC, such as the USA, UK, and Germany, are likely to be underestimating their emissions (Rigby et al, 2010 :10318).

Developed countries are likely under-reporting their emissions because emission reduction legislation relies on a ‘bottom-up’ measurement approach, which greatly underestimates real emissions (Weiss and Prinn, 2011: 1934). There are two broad approaches to measuring emissions: bottom-up and top-down. The bottom-up approach measures SF 6 emissions at the source of emission, while the top-down approach measures changes in the atmospheric concentration of SF 6 . The aforementioned increase in global atmospheric SF 6 emissions was measured and modelled extensively and independently by several research studies (Weiss and Prinn, 2011: 1934). They all came to the same general conclusion, namely that global SF 6 emissions are greatly underestimated by bottom-up emissions reported to the UNFCCC by developed countries (Weiss and Prinn, 2011: 1934).

Considering that the measurement approaches on which emissions regulation is based are fundamentally erroneous, how can we be certain that the SF 6- reduction measures taken so far by the EU, and by extension the electrical industry, have been effective?

Is the mitigation of SF6 emissions difficult? Do better solutions exist?

Due to SF 6 ’s high GWP, its use is regulated by national and international governing bodies (Deux, 2013: 2). This creates further costs and a myriad of bureaucratic compliance legislation for companies, that must be adhered to. For example, when SF 6 -filled equipment is near the end of its life or has technical problems, special care must be taken in its recycling process and maintenance. Only licensed or authorized hazardous waste managers are permitted to handle, transport and recycle the gas according to national or regional regulations and standards (Deux, 2013: 4). These lifecycle management costs will continue to rise as the global demand for electricity, and, thus, switchgear, increases.

With EU regulation No 517/2014 due to be reviewed in 2020, policy makers should campaign for further legislation with the final aim of phasing out SF 6

All the externalities of SF 6 described in this paper have incentivised big and small manufacturers to find SF 6 -free solutions to switchgear. Several manufacturers – predominantly in the medium voltage (MV) level – have developed effective solutions based on vacuum switching technology in combination with solid or air insulation as alternatives for SF 6 (Porte and Schoonenberg, 2009: 1). Rapid innovations in the MV range have brought into question the industry claim that SF 6 is a necessary evil and that alternatives are too costly (Porte and Schoonenberg, 2009: 1). Unfortunately, similar progress has not yet been made for high voltage (HV) applications.

From a pricing perspective, research comparing SF 6 -containing switchgear and SF 6 -free switchgear found no evidence that the latter was more expensive than the former (Benner et al, 2012: 23). In actual fact, it found that SF 6 -free switchgear generally can be up to 10% cheaper than the corresponding SF 6 -containing alternative (Benner et al, 2012: 23).

Conclusion

SF 6 is the most potent greenhouse gas in existence and for this reason was included in the Kyoto Protocol’s list of substances of which the use and emission should be minimized. Consequently, SF 6 has been banned for all applications in which alternatives exist. However, an exception has been made for HV and MV switchgear in the electrical industry.

The rationale for this was that there was no viable alternative. However, as has been made clear this in this paper, this is no longer the case, at least not in the case of MV switchgear. There are alternatives which are technically and commercially viable. With EU regulation No 517/2014 due to be reviewed in 2020, policy makers should campaign for further legislation with the final aim of phasing out SF 6 . This will further invigorate the research and development of SF 6 -free technologies, not only for MV switchgear, but also for HV applications. These measures will represent a significant step in the fight against climate change and also help reestablish Europe as a leader in cleantech.

Editor’s Note

Nicholas Ottersbach is a business developer and researcher at Nuventura, a cleantech startup looking to contribute to a greener, smarter and more sustainable global power sector. The company is involved in developing an alternative for SF 6.

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