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Seb CailleJohn G. Allen. Discovery of Novel Protein Fucosylation Inhibitors and Development of a Manufacturing Process To Prepare Inhibitor 6,6,6-Trifluorofucose. 2016 ,,, 37-68. ,, 37-68. https://doi.org/10.1021/bk-2016-1239.ch002

Tanyu Cheng, Qunqun Ye, Qiankun Zhao, and Guohua Liu . Dynamic Kinetic Resolution of Phthalides via Asymmetric Transfer Hydrogenation: A Strategy Constructs 1,3-Distereocentered 3-(2-Hydroxy-2-arylethyl)isobenzofuran-1(3H)-one. Organic Letters 2015 , 17 (20) , 4972-4975. 17 (20) , 4972-4975. https://doi.org/10.1021/acs.orglett.5b02394

Beatriz Domı́nguez-Pérez, Éric Ferrer, Marta Figueredo, Jean-Didier Maréchal, Jan Balzarini, Ramon Alibés, and Félix Busqué . Synthesis of Novel Nucleoside Analogues Built on a Bicyclo[4.1.0]heptane Scaffold. The Journal of Organic Chemistry 2015 , 80 (19) , 9495-9505. 80 (19) , 9495-9505. https://doi.org/10.1021/acs.joc.5b01413

Andrea Temperini, Anna Barattucci, Paola Maria Bonaccorsi, Ornelio Rosati, and Lucio Minuti . Stereoselective Synthesis of Substituted Tetrahydropyrans and Isochromans by Cyclization of Phenylseleno Alcohols. The Journal of Organic Chemistry 2015 , 80 (16) , 8102-8112. 80 (16) , 8102-8112. https://doi.org/10.1021/acs.joc.5b01199

Mei-Hua Shen, Ke Xu, Chu-Han Sun, and Hua-Dong Xu . The Reaction of 2,3-Dimethylimidazole-1-sulfonyl Azide Triflate with 3-Substituted Indoles: Reactivity and Scope. Organic Letters 2015 , 17 (15) , 3654-3657. 17 (15) , 3654-3657. https://doi.org/10.1021/acs.orglett.5b01464

Dong Wang and Didier Astruc . The Golden Age of Transfer Hydrogenation. Chemical Reviews 2015 , 115 (13) , 6621-6686. 115 (13) , 6621-6686. https://doi.org/10.1021/acs.chemrev.5b00203

Rina Soni, Thomas H. Hall, Benjamin P. Mitchell, Matthew R. Owen, and Martin Wills . Asymmetric Reduction of Electron-Rich Ketones with Tethered Ru(II)/TsDPEN Catalysts Using Formic Acid/Triethylamine or Aqueous Sodium Formate. The Journal of Organic Chemistry 2015 , 80 (13) , 6784-6793. 80 (13) , 6784-6793. https://doi.org/10.1021/acs.joc.5b00990

Vaishali S. Shende, Sudhindra H. Deshpande, Savita K. Shingote, Anu Joseph, and Ashutosh A. Kelkar . Asymmetric Transfer Hydrogenation of Imines in Water by Varying the Ratio of Formic Acid to Triethylamine. Organic Letters 2015 , 17 (12) , 2878-2881. 17 (12) , 2878-2881. https://doi.org/10.1021/acs.orglett.5b00889

Matthias Böge, Christian Fowelin, Patrick Bednarski, and Jürgen Heck . Diaminohexopyranosides as Ligands in Half-Sandwich Ruthenium(II), Rhodium(III), and Iridium(III) Complexes. Organometallics 2015 , 34 (8) , 1507-1521. 34 (8) , 1507-1521. https://doi.org/10.1021/om5013117

Meng Wu, Tanyu Cheng, Min Ji, and Guohua Liu . Ru-Catalyzed Asymmetric Transfer Hydrogenation of α-Trifluoromethylimines. The Journal of Organic Chemistry 2015 , 80 (7) , 3708-3713. 80 (7) , 3708-3713. https://doi.org/10.1021/acs.joc.5b00177

Grant J. Sherborne, Michael R. Chapman, A. John Blacker, Richard A. Bourne, Thomas W. Chamberlain, Benjamin D. Crossley, Stephanie J. Lucas, Patrick C. McGowan, Mark A. Newton, Thomas E. O Screen, Paul Thompson, Charlotte E. Willans, and Bao N. Nguyen . Activation and Deactivation of a Robust Immobilized Cp*Ir-Transfer Hydrogenation Catalyst: A Multielement in Situ X-ray Absorption Spectroscopy Study. Journal of the American Chemical Society 2015 , 137 (12) , 4151-4157. 137 (12) , 4151-4157. https://doi.org/10.1021/ja512868a

Miquel Navarro, Diego Vidal, Pau Clavero, Arnald Grabulosa, and Guillermo Muller . Mild Photochemical Tethering of [RuCl2(η6-arene)P*] Complexes with P-Stereogenic 2-Biphenylylphosphines. Organometallics 2015 , 34 (5) , 973-994. 34 (5) , 973-994. https://doi.org/10.1021/acs.organomet.5b00018

Takeshi Tsuruda, Makoto Ebine, Aya Umeda, and Tohru Oishi . Stereoselective Synthesis of the C1–C29 Part of Amphidinol 3. The Journal of Organic Chemistry 2015 , 80 (2) , 859-871. 80 (2) , 859-871. https://doi.org/10.1021/jo502322m

Masato Komiyama, Takahiro Itoh, and Takumi Takeyasu . Scalable Ruthenium-Catalyzed Asymmetric Synthesis of a Key Intermediate for the β2-Adrenergic Receptor Agonist. Organic Process Research & Development 2015 , 19 (1) , 315-319. 19 (1) , 315-319. https://doi.org/10.1021/op500338d

Sara Sabater, Miguel Baya, and Jose A. Mata . Highly Active Cp*Ir Catalyst at Low Temperatures Bearing an N-Heterocyclic Carbene Ligand and a Chelated Primary Benzylamine in Transfer Hydrogenation. Organometallics 2014 , 33 (23) , 6830-6839. 33 (23) , 6830-6839. https://doi.org/10.1021/om500888d

Dacheng Zhang, Tanyu Cheng, Qiankun Zhao, Jianyou Xu, and Guohua Liu . Highly Enantioselective One-Pot Synthesis of Chiral β-Hydroxy Sulfones via Asymmetric Transfer Hydrogenation in an Aqueous Medium. Organic Letters 2014 , 16 (21) , 5764-5767. 16 (21) , 5764-5767. https://doi.org/10.1021/ol502832a

Roy Hodgkinson, Václav Jurčík, Antonio Zanotti-Gerosa, Hans Günter Nedden, Andrew Blackaby, Guy J. Clarkson, and Martin Wills . Synthesis and Catalytic Applications of an Extended Range of Tethered Ruthenium(II)/η6-Arene/Diamine Complexes. Organometallics 2014 , 33 (19) , 5517-5524. 33 (19) , 5517-5524. https://doi.org/10.1021/om500788t

Seung Hyo Kim and Soon Hyeok Hong . Transfer Hydrogenation of Organic Formates and Cyclic Carbonates: An Alternative Route to Methanol from Carbon Dioxide. ACS Catalysis 2014 , 4 (10) , 3630-3636. 4 (10) , 3630-3636. https://doi.org/10.1021/cs501133m

Om Prakash, Hemant Joshi, Kamal Nayan Sharma, Pancham Lal Gupta, and Ajai K. Singh . Transfer Hydrogenation (pH Independent) of Ketones and Aldehydes in Water with Glycerol: Ru, Rh, and Ir Catalysts with a COOH Group near the Metal on a (Phenylthio)methyl-2-pyridine Scaffold. Organometallics 2014 , 33 (14) , 3804-3812. 33 (14) , 3804-3812. https://doi.org/10.1021/om500515z

Alpesh K. Sharma, Hemant Joshi, Kamal Nayan Sharma, Pancham L. Gupta, and Ajai K. Singh . 2-Propanol vs Glycerol as Hydrogen Source in Catalytic Activation of Transfer Hydrogenation with (η6-Benzene)ruthenium(II) Complexes of Unsymmetrical Bidentate Chalcogen Ligands. Organometallics 2014 , 33 (13) , 3629-3639. 33 (13) , 3629-3639. https://doi.org/10.1021/om500579r

Om Prakash, Kamal Nayan Sharma, Hemant Joshi, Pancham L. Gupta, and Ajai K. Singh . Half-Sandwich Rhodium/Iridium(III) Complexes Designed with Cp* and 1,2-Bis(phenylchalcogenomethyl)benzene as Catalysts for Transfer Hydrogenation in Glycerol. Organometallics 2014 , 33 (10) , 2535-2543. 33 (10) , 2535-2543. https://doi.org/10.1021/om500149n

Fariha Saleem, Gyandshwar Kumar Rao, Arun Kumar, Goutam Mukherjee, and Ajai K. Singh . Catalyst Activation with Cp*RhIII/IrIII–1,2,3-Triazole-Based Organochalcogen Ligand Complexes: Transfer Hydrogenation via Loss of Cp* and N-Methylmorpholine N-Oxide Based vs Oppenauer-Type Oxidation. Organometallics 2014 , 33 (9) , 2341-2351. 33 (9) , 2341-2351. https://doi.org/10.1021/om500266p

Cavan M. Bligh, Luigi Anzalone, Young Chun Jung, Yuegang Zhang, and William A. Nugent . Preparation of Both C5′ Epimers of 5′-C-Methyladenosine: Reagent Control Trumps Substrate Control. The Journal of Organic Chemistry 2014 , 79 (7) , 3238-3243. 79 (7) , 3238-3243. https://doi.org/10.1021/jo500089t

Qian Zhang, Bai-Wei Ma, Qian-Qian Wang, Xing-Xing Wang, Xia Hu, Ming-Sheng Xie, Gui-Rong Qu, and Hai-Ming Guo . The Synthesis of Tenofovir and Its Analogues via Asymmetric Transfer Hydrogenation. Organic Letters 2014 , 16 (7) , 2014-2017. 16 (7) , 2014-2017. https://doi.org/10.1021/ol500583d

Hélène Pellissier and Hervé Clavier . Enantioselective Cobalt-Catalyzed Transformations. Chemical Reviews 2014 , 114 (5) , 2775-2823. 114 (5) , 2775-2823. https://doi.org/10.1021/cr4004055

Yanyun Li, Shenluan Yu, Xiaofeng Wu, Jianliang Xiao, Weiyi Shen, Zhenrong Dong, and Jingxing Gao . Iron Catalyzed Asymmetric Hydrogenation of Ketones. Journal of the American Chemical Society 2014 , 136 (10) , 4031-4039. 136 (10) , 4031-4039. https://doi.org/10.1021/ja5003636

Jesús Campos, Ulrich Hintermair, Timothy P. Brewster, Michael K. Takase, and Robert H. Crabtree . Catalyst Activation by Loss of Cyclopentadienyl Ligands in Hydrogen Transfer Catalysis with Cp*IrIII Complexes. ACS Catalysis 2014 , 4 (3) , 973-985. 4 (3) , 973-985. https://doi.org/10.1021/cs401138f

Om Prakash, Kamal Nayan Sharma, Hemant Joshi, Pancham L. Gupta, and Ajai K. Singh . (η5-Cp*)Rh(III)/Ir(III) Complexes with Bis(chalcogenoethers) (E, E′ Ligands: E = S/Se; E′ = S/Se): Synthesis, Structure, and Applications in Catalytic Oppenauer-Type Oxidation and Transfer Hydrogenation. Organometallics 2014 , 33 (4) , 983-993. 33 (4) , 983-993. https://doi.org/10.1021/om401150s

Robert H. Morris . Estimating the Acidity of Transition Metal Hydride and Dihydrogen Complexes by Adding Ligand Acidity Constants. Journal of the American Chemical Society 2014 , 136 (5) , 1948-1959. 136 (5) , 1948-1959. https://doi.org/10.1021/ja410718r

Michael J. Sgro, Fatme Dahcheh, and Douglas W. Stephan . Synthesis and Reactivity of Ruthenium Hydride Complexes Containing a Tripodal Aminophosphine Ligand. Organometallics 2014 , 33 (2) , 578-586. 33 (2) , 578-586. https://doi.org/10.1021/om4011388

Zhijia Fang and Martin Wills . Asymmetric Reduction of Diynones and the Total Synthesis of (S)-Panaxjapyne A. Organic Letters 2014 , 16 (2) , 374-377. 16 (2) , 374-377. https://doi.org/10.1021/ol4032123

Timothy P. Brewster, Alexander J. M. Miller, D. Michael Heinekey, and Karen I. Goldberg . Hydrogenation of Carboxylic Acids Catalyzed by Half-Sandwich Complexes of Iridium and Rhodium. Journal of the American Chemical Society 2013 , 135 (43) , 16022-16025. 135 (43) , 16022-16025. https://doi.org/10.1021/ja408149n

Rina Soni, Katherine E. Jolley, Guy J. Clarkson, and Martin Wills . Direct Formation of Tethered Ru(II) Catalysts Using Arene Exchange. Organic Letters 2013 , 15 (19) , 5110-5113. 15 (19) , 5110-5113. https://doi.org/10.1021/ol4024979

Zhijia Fang and Martin Wills . Asymmetric Transfer Hydrogenation of Functionalized Acetylenic Ketones. The Journal of Organic Chemistry 2013 , 78 (17) , 8594-8605. 78 (17) , 8594-8605. https://doi.org/10.1021/jo401284c

Yanping Wang and George A. O’Doherty . Cryptocaryols A and B: Total Syntheses, Stereochemical Revision, Structure Elucidation, and Structure–Activity Relationship. Journal of the American Chemical Society 2013 , 135 (25) , 9334-9337. 135 (25) , 9334-9337. https://doi.org/10.1021/ja404401f

Alain J. Simpson and Hon Wai Lam . Enantioselective Nickel-Catalyzed Michael Additions of 2-Acetylazaarenes to Nitroalkenes. Organic Letters 2013 , 15 (11) , 2586-2589. 15 (11) , 2586-2589. https://doi.org/10.1021/ol400578c

K. S. Sandhya and Cherumuttathu H. Suresh . Autotandem Aromatization–Dearomatization Pathways for PNP-RuII-Catalyzed Formation of Imine and Hydrogen from Alcohol and Amine. Organometallics 2013 , 32 (10) , 2926-2933. 32 (10) , 2926-2933. https://doi.org/10.1021/om4001428

C. Guy Goodman, Dung T. Do, and Jeffrey S. Johnson . Asymmetric Synthesis of anti-β-Amino-α-Hydroxy Esters via Dynamic Kinetic Resolution of β-Amino-α-Keto Esters. Organic Letters 2013 , 15 (10) , 2446-2449. 15 (10) , 2446-2449. https://doi.org/10.1021/ol4009206

Chada Raji Reddy, Enukonda Jithender, and Kothakonda Rajendra Prasad . Total Syntheses of the Proposed Structure for Ieodoglucomides A and B. The Journal of Organic Chemistry 2013 , 78 (9) , 4251-4260. 78 (9) , 4251-4260. https://doi.org/10.1021/jo400041p

Stephen K. Murphy and Vy M. Dong . Enantioselective Ketone Hydroacylation Using Noyori’s Transfer Hydrogenation Catalyst. Journal of the American Chemical Society 2013 , 135 (15) , 5553-5556. 135 (15) , 5553-5556. https://doi.org/10.1021/ja4021974

Elizabeth H. Krenske and K. N. Houk . Aromatic Interactions as Control Elements in Stereoselective Organic Reactions. Accounts of Chemical Research 2013 , 46 (4) , 979-989. 46 (4) , 979-989. https://doi.org/10.1021/ar3000794

Andrea Kišić, Michel Stephan, and Barbara Mohar . Asymmetric Transfer Hydrogenation of 1-Naphthyl Ketones by an ansa-Ru(II) Complex of a DPEN-SO2N(Me)-(CH2)2(η6-p-Tol) Combined Ligand. Organic Letters 2013 , 15 (7) , 1614-1617. 15 (7) , 1614-1617. https://doi.org/10.1021/ol400393j

Pavel A. Dub and Takao Ikariya . Quantum Chemical Calculations with the Inclusion of Nonspecific and Specific Solvation: Asymmetric Transfer Hydrogenation with Bifunctional Ruthenium Catalysts. Journal of the American Chemical Society 2013 , 135 (7) , 2604-2619. 135 (7) , 2604-2619. https://doi.org/10.1021/ja3097674

Michael T. Corbett and Jeffrey S. Johnson . Diametric Stereocontrol in Dynamic Catalytic Reduction of Racemic Acyl Phosphonates: Divergence from α-Keto Ester Congeners. Journal of the American Chemical Society 2013 , 135 (2) , 594-597. 135 (2) , 594-597. https://doi.org/10.1021/ja310980q

Kimberly M. Steward, Michael T. Corbett, C. Guy Goodman, and Jeffrey S. Johnson . Asymmetric Synthesis of Diverse Glycolic Acid Scaffolds via Dynamic Kinetic Resolution of α-Keto Esters. Journal of the American Chemical Society 2012 , 134 (49) , 20197-20206. 134 (49) , 20197-20206. https://doi.org/10.1021/ja3102709

Tarn C. Johnson, William G. Totty, and Martin Wills . Application of Ruthenium Complexes of Triazole-Containing Tridentate Ligands to Asymmetric Transfer Hydrogenation of Ketones. Organic Letters 2012 , 14 (20) , 5230-5233. 14 (20) , 5230-5233. https://doi.org/10.1021/ol302354z

Sarah Z. Tasker, Michael A. Bosscher, Christina A. Shandro, Erica L. Lanni, Keun Ah Ryu, Gregory S. Snapper, Jarrad M. Utter, Bruce A. Ellsworth, and Carolyn E. Anderson . Preparation of N-Alkyl 2-Pyridones via a Lithium Iodide Promoted O- to N-Alkyl Migration: Scope and Mechanism. The Journal of Organic Chemistry 2012 , 77 (18) , 8220-8230. 77 (18) , 8220-8230. https://doi.org/10.1021/jo3015424

Petr Šot, Marek Kuzma, Jiří Václavík, Jan Pecháček, Jan Přech, Jakub Januščák, and Petr Kačer . Asymmetric Transfer Hydrogenation of Acetophenone N-Benzylimine Using [RuIICl((S,S)-TsDPEN)(η6-p-cymene)]: A DFT Study. Organometallics 2012 , 31 (17) , 6496-6499. 31 (17) , 6496-6499. https://doi.org/10.1021/om300413n

Martin A. Ariger and Erick M. Carreira . pH-Independent Transfer Hydrogenation in Water: Catalytic, Enantioselective Reduction of β-Keto Esters. Organic Letters 2012 , 14 (17) , 4522-4524. 14 (17) , 4522-4524. https://doi.org/10.1021/ol301903c

Kimberly M. Steward, Emily C. Gentry, and Jeffrey S. Johnson . Dynamic Kinetic Resolution of α-Keto Esters via Asymmetric Transfer Hydrogenation. Journal of the American Chemical Society 2012 , 134 (17) , 7329-7332. 134 (17) , 7329-7332. https://doi.org/10.1021/ja3027136

Daniel Carmona, Fernando J. Lahoz, Pilar García-Orduña, and Luis A. Oro , M. Pilar Lamata and Fernando Viguri . Half-Sandwich Complexes of Osmium(II) with l-α-Amino Carboxylate Ligands as Asymmetric Transfer Hydrogenation Catalysts. On the Origin of the Enantioselectivity. Organometallics 2012 , 31 (8) , 3333-3345. 31 (8) , 3333-3345. https://doi.org/10.1021/om3001394

Caroline Roe, Heather Hobbs, and Robert A. Stockman . One-Pot Synthesis of Chiral Nonracemic Amines. The Journal of Organic Chemistry 2011 , 76 (22) , 9452-9459. 76 (22) , 9452-9459. https://doi.org/10.1021/jo201849j

M. Victoria Jiménez, Javier Fernández-Tornos, Jesús J. Pérez-Torrente, Francisco J. Modrego, Sonja Winterle, Carmen Cunchillos, Fernando J. Lahoz, and Luis A. Oro . Iridium(I) Complexes with Hemilabile N-Heterocyclic Carbenes: Efficient and Versatile Transfer Hydrogenation Catalysts. Organometallics 2011 , 30 (20) , 5493-5508. 30 (20) , 5493-5508. https://doi.org/10.1021/om200747k

Taichiro Touge, Tomohiko Hakamata, Hideki Nara, Tohru Kobayashi, Noboru Sayo, Takao Saito, Yoshihito Kayaki, and Takao Ikariya . Oxo-Tethered Ruthenium(II) Complex as a Bifunctional Catalyst for Asymmetric Transfer Hydrogenation and H2 Hydrogenation. Journal of the American Chemical Society 2011 , 133 (38) , 14960-14963. 133 (38) , 14960-14963. https://doi.org/10.1021/ja207283t

Peter E. Sues, Alan J. Lough, and Robert H. Morris . Stereoelectronic Factors in Iron Catalysis: Synthesis and Characterization of Aryl-Substituted Iron(II) Carbonyl P–N–N–P Complexes and Their Use in the Asymmetric Transfer Hydrogenation of Ketones. Organometallics 2011 , 30 (16) , 4418-4431. 30 (16) , 4418-4431. https://doi.org/10.1021/om2005172

Rina Soni, John-Michael Collinson, Guy C. Clarkson, and Martin Wills . An Unexpected Directing Effect in the Asymmetric Transfer Hydrogenation of α,α-Disubstituted Ketones. Organic Letters 2011 , 13 (16) , 4304-4307. 13 (16) , 4304-4307. https://doi.org/10.1021/ol201643v

Fei Chen, Ziyuan Ding, Jie Qin, Tianli Wang, Yanmei He, and Qing-Hua Fan . Highly Effective Asymmetric Hydrogenation of Cyclic N-Alkyl Imines with Chiral Cationic Ru-MsDPEN Catalysts. Organic Letters 2011 , 13 (16) , 4348-4351. 13 (16) , 4348-4351. https://doi.org/10.1021/ol201679f

Yohei Adachi, Noriyuki Kamei, Satoshi Yokoshima, and Tohru Fukuyama . Total Synthesis of (−)-Histrionicotoxin. Organic Letters 2011 , 13 (16) , 4446-4449. 13 (16) , 4446-4449. https://doi.org/10.1021/ol2018032

Mar Gómez-Gallego and Miguel A. Sierra . Kinetic Isotope Effects in the Study of Organometallic Reaction Mechanisms. Chemical Reviews 2011 , 111 (8) , 4857-4963. 111 (8) , 4857-4963. https://doi.org/10.1021/cr100436k

Javier Torres, Francisco Sepúlveda, M. Carmen Carrión, Félix A. Jalón, Blanca R. Manzano, Ana M. Rodríguez, Afrooz Zirakzadeh, Walter Weissensteiner, Antonio E. Mucientes, and M. Angeles de la Peña . Ruthenium Arene Derivatives of Chiral Ferrocene-Based P,N or P,O Ligands. Transformation of Chloro–Alcohol into Hydrido–Carbonyl Complexes. Organometallics 2011 , 30 (13) , 3490-3503. 30 (13) , 3490-3503. https://doi.org/10.1021/om1008132

Tianli Wang, Lian-Gang Zhuo, Zhiwei Li, Fei Chen, Ziyuan Ding, Yanmei He, Qing-Hua Fan, Junfeng Xiang, Zhi-Xiang Yu, and Albert S. C. Chan . Highly Enantioselective Hydrogenation of Quinolines Using Phosphine-Free Chiral Cationic Ruthenium Catalysts: Scope, Mechanism, and Origin of Enantioselectivity. Journal of the American Chemical Society 2011 , 133 (25) , 9878-9891. 133 (25) , 9878-9891. https://doi.org/10.1021/ja2023042

Neil A. Strotman, Carl A. Baxter, Karel M. J. Brands, Ed Cleator, Shane W. Krska, Robert A. Reamer, Debra J. Wallace, and Timothy J. Wright . Reaction Development and Mechanistic Study of a Ruthenium Catalyzed Intramolecular Asymmetric Reductive Amination en Route to the Dual Orexin Inhibitor Suvorexant (MK-4305). Journal of the American Chemical Society 2011 , 133 (21) , 8362-8371. 133 (21) , 8362-8371. https://doi.org/10.1021/ja202358f

Yusuke Sunada, Tsuyoshi Imaoka, and Hideo Nagashima . Half-Sandwich (η6-Arene)iron(II) Dinitrogen Complexes Bearing a Disilaferracycle Skeleton as a Precursor for Double Silylation of Ethylene and Alkynes. Organometallics 2010 , 29 (23) , 6157-6160. 29 (23) , 6157-6160. https://doi.org/10.1021/om100889w

Ilya D. Gridnev, Masahito Watanabe, Hui Wang, and Takao Ikariya. Mechanism of Enantioselective C−C Bond Formation with Bifunctional Chiral Ru Catalysts: NMR and DFT Study. Journal of the American Chemical Society 2010 , 132 (46) , 16637-16650. 132 (46) , 16637-16650. https://doi.org/10.1021/ja107597w

Damien Cartigny, Kurt Püntener, Tahar Ayad, Michelangelo Scalone and Virginie Ratovelomanana-Vidal. Highly Diastereo- and Enantioselective Synthesis of Monodifferentiated syn-1,2-Diol Derivatives through Asymmetric Transfer Hydrogenation via Dynamic Kinetic Resolution. Organic Letters 2010 , 12 (17) , 3788-3791. 12 (17) , 3788-3791. https://doi.org/10.1021/ol101451s

Omid Soltani, Martin A. Ariger, Henar Vázquez-Villa and Erick M. Carreira. Transfer Hydrogenation in Water: Enantioselective, Catalytic Reduction of α-Cyano and α-Nitro Substituted Acetophenones. Organic Letters 2010 , 12 (13) , 2893-2895. 12 (13) , 2893-2895. https://doi.org/10.1021/ol1008894

Xuefeng Li, Liangchun Li, Yuanfu Tang, Ling Zhong, Linfeng Cun, Jin Zhu, Jian Liao and Jingen Deng . Chemoselective Conjugate Reduction of α,β-Unsaturated Ketones Catalyzed by Rhodium Amido Complexes in Aqueous Media. The Journal of Organic Chemistry 2010 , 75 (9) , 2981-2988. 75 (9) , 2981-2988. https://doi.org/10.1021/jo100256t

Ming Lei, Wenchao Zhang, Yue Chen and Yanhui Tang . Preference of H2 as Hydrogen Source in Hydrogenation of Ketones Catalyzed by Late Transition Metal Complexes. A DFT Study. Organometallics 2010 , 29 (3) , 543-548. 29 (3) , 543-548. https://doi.org/10.1021/om900434n

Rongwei Guo, Shuiming Lu, Xuanhua Chen, Chi-Wing Tsang, Wenli Jia, Christine Sui-Seng, Dino Amoroso and Kamaluddin Abdur-Rashid. Synthesis of Chiral Aminophosphines from Chiral Aminoalcohols via Cyclic Sulfamidates. The Journal of Organic Chemistry 2010 , 75 (3) , 937-940. 75 (3) , 937-940. https://doi.org/10.1021/jo902302c

Shuanhu Gao, Qiaoling Wang, Lily Jun-Shen Huang, Lawrence Lum and Chuo Chen . Chemical and Biological Studies of Nakiterpiosin and Nakiterpiosinone. Journal of the American Chemical Society 2010 , 132 (1) , 371-383. 132 (1) , 371-383. https://doi.org/10.1021/ja908626k

Wylie W. N. O, Alan J. Lough and Robert H. Morris. Transmetalation of a Primary Amino-Functionalized N-Heterocyclic Carbene Ligand from an Axially Chiral Square-Planar Nickel(II) Complex to a Ruthenium(II) Precatalyst for the Transfer Hydrogenation of Ketones. Organometallics 2009 , 28 (23) , 6755-6761. 28 (23) , 6755-6761. https://doi.org/10.1021/om9007746

Bo Zhang, Ming-Hua Xu and Guo-Qiang Lin. Catalytic Enantioselective Synthesis of Chiral Phthalides by Efficient Reductive Cyclization of 2-Acylarylcarboxylates under Aqueous Transfer Hydrogenation Conditions. Organic Letters 2009 , 11 (20) , 4712-4715. 11 (20) , 4712-4715. https://doi.org/10.1021/ol901674k

Omid Soltani, Martin A. Ariger and Erick M. Carreira. Transfer Hydrogenation in Water: Enantioselective, Catalytic Reduction of (E)-β,β-Disubstituted Nitroalkenes. Organic Letters 2009 , 11 (18) , 4196-4198. 11 (18) , 4196-4198. https://doi.org/10.1021/ol901332e

Damien Arquier, Laure Vendier, Karinne Miqueu, Jean-Marc Sotiropoulos, Stéphanie Bastin and Alain Igau . Crucial Role of the Amidine Moiety in Methylenamino Phosphine-Type Ligands for the Synthesis of Tethered η6-Arene-η1-P Ruthenium(II) Complexes: Experimental and Theoretical Studies. Organometallics 2009 , 28 (17) , 4945-4957. 28 (17) , 4945-4957. https://doi.org/10.1021/om900231c

Daisuke Aburano, Fuyuhiko Inagaki, Shoichirou Tomonaga and Chisato Mukai. Synthesis of a Core Carbon Framework of Cyanosporasides A and B. The Journal of Organic Chemistry 2009 , 74 (15) , 5590-5594. 74 (15) , 5590-5594. https://doi.org/10.1021/jo901141t

David J. Morris, Guy J. Clarkson and Martin Wills. Insights into Hydrogen Generation from Formic Acid Using Ruthenium Complexes. Organometallics 2009 , 28 (14) , 4133-4140. 28 (14) , 4133-4140. https://doi.org/10.1021/om900099u

M. Carmen Carrión, Francisco Sepúlveda, Félix A. Jalón and Blanca R. Manzano, Ana M. Rodríguez. Base-Free Transfer Hydrogenation of Ketones Using Arene Ruthenium(II) Complexes. Organometallics 2009 , 28 (13) , 3822-3833. 28 (13) , 3822-3833. https://doi.org/10.1021/om9001268

Fabio Marchetti, Claudio Pettinari, Adele Cerquetella, Augusto Cingolani, Riccardo Pettinari, Magda Monari, Riccardo Wanke, Maxim L. Kuznetsov and Armando J. L. Pombeiro . Switching between κ2 and κ3 Bis(pyrazol-1-yl)acetate Ligands by Tuning Reaction Conditions: Synthesis, Spectral, Electrochemical, Structural, and Theoretical Studies on Arene-Ru(II) Derivatives of Bis(azol-1-yl)acetate Ligands. Inorganic Chemistry 2009 , 48 (13) , 6096-6108. 48 (13) , 6096-6108. https://doi.org/10.1021/ic900463b

Sadagopan Raghavan, Shaik Mustafa and B. Sridhar. A Versatile Route to (E)- and (Z)-2-Hydroxy-3,4-unsaturated Disubstituted Sulfilimines and Their Haloamidation Reaction. The Journal of Organic Chemistry 2009 , 74 (12) , 4499-4507. 74 (12) , 4499-4507. https://doi.org/10.1021/jo900569z

Yue Chen, Yanhui Tang, Shubin Liu, Ming Lei and Weihai Fang. Mechanism and Influence of Acid in Hydrogenation of Ketones by η6-Arene/N-Tosylethylenediamine Ruthenium(II). Organometallics 2009 , 28 (7) , 2078-2084. 28 (7) , 2078-2084. https://doi.org/10.1021/om8012212

Fanlong Zeng and Zhengkun Yu . Construction of Highly Active Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Supported Pyrazolyl-Imidazolyl Ligand for Transfer Hydrogenation of Ketones. Organometallics 2009 , 28 (6) , 1855-1862. 28 (6) , 1855-1862. https://doi.org/10.1021/om801080p

A. John Blacker, Simon B. Duckett, Jake Grace, Robin N. Perutz and Adrian C. Whitwood. Reactivity, Structures, and NMR Spectroscopy of Half-Sandwich Pentamethylcyclopentadienyl Rhodium Amido Complexes Relevant to Transfer Hydrogenation. Organometallics 2009 , 28 (5) , 1435-1446. 28 (5) , 1435-1446. https://doi.org/10.1021/om8009969

Gianluca Ciancaleoni, Cristiano Zuccaccia, Daniele Zuccaccia, Eric Clot and Alceo Macchioni . Self-Aggregation Tendency of All Species Involved in the Catalytic Cycle of Bifunctional Transfer Hydrogenation. Organometallics 2009 , 28 (4) , 960-967. 28 (4) , 960-967. https://doi.org/10.1021/om8009552

José E. D. Martins, Guy J. Clarkson and Martin Wills . Ru(II) Complexes of N-Alkylated TsDPEN Ligands in Asymmetric Transfer Hydrogenation of Ketones and Imines. Organic Letters 2009 , 11 (4) , 847-850. 11 (4) , 847-850. https://doi.org/10.1021/ol802801p

Satoshi Minakata and Mitsuo Komatsu. Organic Reactions on Silica in Water. Chemical Reviews 2009 , 109 (2) , 711-724. 109 (2) , 711-724. https://doi.org/10.1021/cr8003955

Kevin H. Shaughnessy. Hydrophilic Ligands and Their Application in Aqueous-Phase Metal-Catalyzed Reactions. Chemical Reviews 2009 , 109 (2) , 643-710. 109 (2) , 643-710. https://doi.org/10.1021/cr800403r

Ryo Akiyama and Shu̅ Kobayashi. “Microencapsulated” and Related Catalysts for Organic Chemistry and Organic Synthesis. Chemical Reviews 2009 , 109 (2) , 594-642. 109 (2) , 594-642. https://doi.org/10.1021/cr800529d

Shin-yo Shirai, Hideki Nara, Yoshihito Kayaki and Takao Ikariya. Remarkable Positive Effect of Silver Salts on Asymmetric Hydrogenation of Acyclic Imines with Cp*Ir Complexes Bearing Chiral N-Sulfonylated Diamine Ligands. Organometallics 2009 , 28 (3) , 802-809. 28 (3) , 802-809. https://doi.org/10.1021/om800926p

Ji Zhang, Peter G. Blazecka, Michelle M. Bruendl and Yun Huang. Ru-TsDPEN with Formic Acid/Hünig’s Base for Asymmetric Transfer Hydrogenation, a Practical Synthesis of Optically Enriched N-Propyl Pantolactam. The Journal of Organic Chemistry 2009 , 74 (3) , 1411-1414. 74 (3) , 1411-1414. https://doi.org/10.1021/jo802380j

Shuanhu Gao, Qiaoling Wang and Chuo Chen. Synthesis and Structure Revision of Nakiterpiosin. Journal of the American Chemical Society 2009 , 131 (4) , 1410-1412. 131 (4) , 1410-1412. https://doi.org/10.1021/ja808110d

Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Adele Cerquetella, Corrado Di Nicola, Alceo Macchioni, Daniele Zuccaccia, Magda Monari and Fabio Piccinelli. Synthesis and Intramolecular and Interionic Structural Characterization of Half-Sandwich (Arene)Ruthenium(II) Derivatives of Bis(Pyrazolyl)Alkanes. Inorganic Chemistry 2008 , 47 (24) , 11593-11603. 47 (24) , 11593-11603. https://doi.org/10.1021/ic801150c

Ting-Ke Zhang, Dong-Liang Mo, Li-Xin Dai and Xue-Long Hou . Palladacycle-Catalyzed Highly Efficient Kinetic Resolution of 1-Hydroxy-2-aryl-1,2-dihydronaphthalenes via Dehydration Reaction. Organic Letters 2008 , 10 (23) , 5337-5340. 10 (23) , 5337-5340. https://doi.org/10.1021/ol801946e

Nicolas Pannetier, Jean-Baptiste Sortais, Pape Sylla Dieng, Laurent Barloy, Claude Sirlin and Michel Pfeffer. Kinetics and Mechanism of Ruthenacycle-Catalyzed Asymmetric Hydrogen Transfer. Organometallics 2008 , 27 (22) , 5852-5859. 27 (22) , 5852-5859. https://doi.org/10.1021/om800420r

Immo Weber, Frank W. Heinemann, Walter Bauer, Stefano Superchi, Achim Zahl, Daniela Richter and Ulrich Zenneck. Diastereoselective Routes to [Amino{σ(P):η6-(ansa-phosphinite)benzene}chlororuthenium(II)] PF6 Salts: Kinetic versus Thermodynamic Preferences. Organometallics 2008 , 27 (16) , 4116-4125. 27 (16) , 4116-4125. https://doi.org/10.1021/om701257m

Aaron M. Tondreau, Emil Lobkovsky and Paul J. Chirik. Bis(imino)pyridine Iron Complexes for Aldehyde and Ketone Hydrosilylation. Organic Letters 2008 , 10 (13) , 2789-2792. 10 (13) , 2789-2792. https://doi.org/10.1021/ol800906b

Takayoshi Arai, Ryuta Takashita, Yoko Endo, Masahiko Watanabe and Akira Yanagisawa. Asymmetric Syn-Selective Henry Reaction Catalyzed by the Sulfonyldiamine−CuCl−Pyridine System. The Journal of Organic Chemistry 2008 , 73 (13) , 4903-4906. 73 (13) , 4903-4906. https://doi.org/10.1021/jo800412x

Fanlong Zeng and Zhengkun Yu. Exceptionally Efficient Unsymmetrical Ruthenium(II) NNN Complex Catalysts Bearing a Pyridyl-Based Pyrazolyl−Imidazolyl Ligand for Transfer Hydrogenation of Ketones. Organometallics 2008 , 27 (13) , 2898-2901. 27 (13) , 2898-2901. https://doi.org/10.1021/om8002043

Sachiko Arita, Takashi Koike, Yoshihito Kayaki and Takao Ikariya. Synthesis and Reactivities of Cp*Ir Amide and Hydride Complexes Bearing C−N Chelate Ligands. Organometallics 2008 , 27 (12) , 2795-2802. 27 (12) , 2795-2802. https://doi.org/10.1021/om800124f

Emmanuelle Mothes, Stephane Sentets, Maria Asuncion Luquin, René Mathieu, Noël Lugan and Guy Lavigne. New Insight into the Reactivity of Pyridine-Functionalized Phosphine Complexes of Ruthenium(II) with Respect to Olefin Metathesis and Transfer Hydrogenation. Organometallics 2008 , 27 (6) , 1193-1206. 27 (6) , 1193-1206. https://doi.org/10.1021/om7012106

Takao Ikariya and A. John Blacker . Asymmetric Transfer Hydrogenation of Ketones with Bifunctional Transition Metal-Based Molecular Catalysts. Accounts of Chemical Research 2007 , 40 (12) , 1300-1308. 40 (12) , 1300-1308. https://doi.org/10.1021/ar700134q

Martin Althaus,, Claus Becker,, Antonio Togni, and, Antonio Mezzetti . Ruthenium-Catalyzed Asymmetric Electrophilic Fluorination of 1,3-Dicarbonyl Compounds. Organometallics 2007 , 26 (24) , 5902-5911. 26 (24) , 5902-5911. https://doi.org/10.1021/om700714u

M. Esther Morilla,, Pilar Rodríguez,, Tomás R. Belderrain,, Claudia Graiff,, Antonio Tiripicchio,, M. Carmen Nicasio, and, Pedro J. Pérez . Synthesis, Characterization, and Reactivity of Ruthenium Diene/Diamine Complexes Including Catalytic Hydrogenation of Ketones. Inorganic Chemistry 2007 , 46 (22) , 9405-9414. 46 (22) , 9405-9414. https://doi.org/10.1021/ic701363g

Hannah C. Maytum,, Bahareh Tavassoli, and, Jonathan M. J. Williams . Reduction of Aldehydes and Ketones by Transfer Hydrogenation with 1,4-Butanediol. Organic Letters 2007 , 9 (21) , 4387-4389. 9 (21) , 4387-4389. https://doi.org/10.1021/ol702029n

Fung K. Cheung,, Changxue Lin,, Franco Minissi,, Adriana Lorente Crivillé,, Mark A. Graham,, David J. Fox, and, Martin Wills . An Investigation into the Tether Length and Substitution Pattern of Arene-Substituted Complexes for Asymmetric Transfer Hydrogenation of Ketones. Organic Letters 2007 , 9 (22) , 4659-4662. 9 (22) , 4659-4662. https://doi.org/10.1021/ol702226j

Fung Kei Cheung,, Mark A. Graham,, Franco Minissi, and, Martin Wills . “Ether-Linked” Organometallic Catalysts for Ketone Reduction Reactions. Organometallics 2007 , 26 (22) , 5346-5351. 26 (22) , 5346-5351. https://doi.org/10.1021/om700610y

Vasile I. Pârvulescu and, Christopher Hardacre . Catalysis in Ionic Liquids. Chemical Reviews 2007 , 107 (6) , 2615-2665. 107 (6) , 2615-2665. https://doi.org/10.1021/cr050948h

Jan-Willem Handgraaf and, Evert Jan Meijer . Realistic Modeling of Ruthenium-Catalyzed Transfer Hydrogenation. Journal of the American Chemical Society 2007 , 129 (11) , 3099-3103. 129 (11) , 3099-3103. https://doi.org/10.1021/ja062359e

Hiroyoshi Esaki,, Rumi Ohtaki,, Tomohiro Maegawa,, Yasunari Monguchi, and, Hironao Sajiki . Novel Pd/C-Catalyzed Redox Reactions between Aliphatic Secondary Alcohols and Ketones under Hydrogenation Conditions: Application to H−D Exchange Reaction and the Mechanistic Study. The Journal of Organic Chemistry 2007 , 72 (6) , 2143-2150. 72 (6) , 2143-2150. https://doi.org/10.1021/jo062582u

Joaquim Mola,, Montserrat Rodríguez, and, Isabel Romero, , Antoni Llobet, , Teodor Parella, , Albert Poater,, Miquel Duran, and, Miquel Solà, , Jordi Benet-Buchholz . New Ru Complexes Containing the N-Tridentate bpea and Phosphine Ligands: Consequences of Meridional vs Facial Geometry. Inorganic Chemistry 2006 , 45 (26) , 10520-10529. 45 (26) , 10520-10529. https://doi.org/10.1021/ic061126l

Damjan Šterk,, Michel Stephan, and, Barbara Mohar . Highly Enantioselective Transfer Hydrogenation of Fluoroalkyl Ketones. Organic Letters 2006 , 8 (26) , 5935-5938. 8 (26) , 5935-5938. https://doi.org/10.1021/ol062358r

David J. Morris,, Aidan M. Hayes, and, Martin Wills . The “Reverse-Tethered” Ruthenium (II) Catalyst for Asymmetric Transfer Hydrogenation: Further Applications. The Journal of Organic Chemistry 2006 , 71 (18) , 7035-7044. 71 (18) , 7035-7044. https://doi.org/10.1021/jo061154l

Robert J. Nielsen and, William A. Goddard III . Mechanism of the Aerobic Oxidation of Alcohols by Palladium Complexes of N-Heterocyclic Carbenes. Journal of the American Chemical Society 2006 , 128 (30) , 9651-9660. 128 (30) , 9651-9660. https://doi.org/10.1021/ja060915z

Zaheer E. Clarke,, Paul T. Maragh,, Tara P. Dasgupta,, Dmitry G. Gusev,, Alan J. Lough, and, Kamaluddin Abdur-Rashid . A Family of Active Iridium Catalysts for Transfer Hydrogenation of Ketones. Organometallics 2006 , 25 (17) , 4113-4117. 25 (17) , 4113-4117. https://doi.org/10.1021/om060049z

Kevin McEleney,, Daryl P. Allen,, Alison E. Holliday, and, Cathleen M. Crudden . Functionalized Mesoporous Silicates for the Removal of Ruthenium from Reaction Mixtures. Organic Letters 2006 , 8 (13) , 2663-2666. 8 (13) , 2663-2666. https://doi.org/10.1021/ol060389g

Ingo Schiffers,, Toni Rantanen,, Frank Schmidt,, Werner Bergmans,, Lorenzo Zani, and, Carsten Bolm . Resolution of Racemic 2-Aminocyclohexanol Derivatives and Their Application as Ligands in Asymmetric Catalysis. The Journal of Organic Chemistry 2006 , 71 (6) , 2320-2331. 71 (6) , 2320-2331. https://doi.org/10.1021/jo052433w

Takao Shibasaki,, Nobuyuki Komine,, Masafumi Hirano, and, Sanshiro Komiya . Synthesis of Mono-, Di-, and Triruthenium(0) Complexes Having a Triphenylene Ligand. Organometallics 2006 , 25 (2) , 523-527. 25 (2) , 523-527. https://doi.org/10.1021/om050875s

Fei Wang,, Hui Liu,, Linfeng Cun,, Jin Zhu,, Jingen Deng, and, Yaozhong Jiang . Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Hydrophobic Metal−Amido Complexes in Aqueous Micelles and Vesicles. The Journal of Organic Chemistry 2005 , 70 (23) , 9424-9429. 70 (23) , 9424-9429. https://doi.org/10.1021/jo0514826

Paolo Pelagatti,, Mauro Carcelli,, Francesca Calbiani,, Claudio Cassi,, Lisa Elviri,, Corrado Pelizzi,, Umberto Rizzotti, and, Dominga Rogolino . Transfer Hydrogenation of Acetophenone Catalyzed by Half-Sandwich Ruthenium(II) Complexes Containing Amino Amide Ligands. Detection of the Catalytic Intermediates by Electrospray Ionization Mass Spectrometry. Organometallics 2005 , 24 (24) , 5836-5844. 24 (24) , 5836-5844. https://doi.org/10.1021/om050519+

Yohei Matsukawa,, Minoru Isobe,, Hiyoshizo Kotsuki, and, Yoshiyasu Ichikawa . Synthesis of (+)-Conagenin. The Journal of Organic Chemistry 2005 , 70 (13) , 5339-5341. 70 (13) , 5339-5341. https://doi.org/10.1021/jo050407s

Aidan M. Hayes,, David J. Morris,, Guy J. Clarkson, and, Martin Wills . A Class of Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenations of Ketones. Journal of the American Chemical Society 2005 , 127 (20) , 7318-7319. 127 (20) , 7318-7319. https://doi.org/10.1021/ja051486s

Masato Ito,, Sachiko Kitahara, and, Takao Ikariya . Cp*Ru(PN) Complex-Catalyzed Isomerization of Allylic Alcohols and Its Application to the Asymmetric Synthesis of Muscone. Journal of the American Chemical Society 2005 , 127 (17) , 6172-6173. 127 (17) , 6172-6173. https://doi.org/10.1021/ja050770g

Dong Xue,, Ying-Chun Chen,, Xin Cui,, Qi-Wei Wang,, Jin Zhu, and, Jin-Gen Deng . Transfer Hydrogenation of Activated CC Bonds Catalyzed by Ruthenium Amido Complexes: Reaction Scope, Limitation, and Enantioselectivity. The Journal of Organic Chemistry 2005 , 70 (9) , 3584-3591. 70 (9) , 3584-3591. https://doi.org/10.1021/jo0478205

Fung Kei (Kathy) Cheung,, Aidan M. Hayes,, Jerome Hannedouche,, Aveline S. Y. Yim, and, Martin Wills . “Tethered” Ru(II) Catalysts for Asymmetric Transfer Hydrogenation of Ketones. The Journal of Organic Chemistry 2005 , 70 (8) , 3188-3197. 70 (8) , 3188-3197. https://doi.org/10.1021/jo050032a

Jean-Baptiste Sortais,, Vincent Ritleng,, Adeline Voelklin,, Alexandre Holuigue,, Hakima Smail,, Laurent Barloy,, Claude Sirlin,, Gerard K. M. Verzijl,, Jeroen A. F. Boogers,, André H. M. de Vries,, Johannes G. de Vries, and, Michel Pfeffer . Cycloruthenated Primary and Secondary Amines as Efficient Catalyst Precursors for Asymmetric Transfer Hydrogenation. Organic Letters 2005 , 7 (7) , 1247-1250. 7 (7) , 1247-1250. https://doi.org/10.1021/ol047353d

Zhen-Rong Dong,, Yan-Yun Li,, Jian-Shan Chen,, Bao-Zhu Li,, Yan Xing, and, Jing-Xing Gao . Highly Efficient Iridium Catalyst for Asymmetric Transfer Hydrogenation of Aromatic Ketones under Base-Free Conditions. Organic Letters 2005 , 7 (6) , 1043-1045. 7 (6) , 1043-1045. https://doi.org/10.1021/ol047412n

Sonja S. Mackey,, Haifeng Wu,, Michael E. Matison, and, Michael Goble . Chemistry Development of a Convergent Route to Trecetilide Hemi-Fumarate. Organic Process Research & Development 2005 , 9 (2) , 174-178. 9 (2) , 174-178. https://doi.org/10.1021/op049799f

Takashi Koike and, Takao Ikariya . Reaction of 16-Electron Ruthenium and Iridium Amide Complexes with Acidic Alcohols: Intramolecular C−H Bond Activation and the Isolation of Cyclometalated Complexes. Organometallics 2005 , 24 (4) , 724-730. 24 (4) , 724-730. https://doi.org/10.1021/om049205x

Corinne Daguenet and, Paul J. Dyson . Inhibition of Catalytic Activity in Ionic Liquids: Implications for Catalyst Design and the Effect of Cosolvents. Organometallics 2004 , 23 (26) , 6080-6083. 23 (26) , 6080-6083. https://doi.org/10.1021/om049347r

Agustín Caballero,, Félix A. Jalón,, Blanca R. Manzano,, Gustavo Espino,, Mercedes Pérez-Manrique,, Antonio Mucientes,, Francisco J. Poblete, and, Miguel Maestro . Ruthenium Arene Derivatives with PN Hemilabile Ligands. P−C Cleavage and Phosphine to Phosphinite Transformation. Organometallics 2004 , 23 (24) , 5694-5706. 23 (24) , 5694-5706. https://doi.org/10.1021/om049438o

Xiuyan Sun,, George Manos,, John Blacker,, Juliette Martin, and, Asterios Gavriilidis . Asymmetric Transfer Hydrogenation of Acetophenone with 1R,2S-Aminoindanol/Pentamethylcyclopentadienylrhodium Catalyst. Organic Process Research & Development 2004 , 8 (6) , 909-914. 8 (6) , 909-914. https://doi.org/10.1021/op0499066

Takayuki Hamada,, Takayoshi Torii,, Tomoyuki Onishi,, Kunisuke Izawa, and, Takao Ikariya . Asymmetric Transfer Hydrogenation of α-Aminoalkyl α‘-Chloromethyl Ketones with Chiral Rh Complexes. The Journal of Organic Chemistry 2004 , 69 (21) , 7391-7394. 69 (21) , 7391-7394. https://doi.org/10.1021/jo0491455

Masahito Watanabe,, Ayako Ikagawa,, Hui Wang,, Kunihiko Murata, and, Takao Ikariya . Catalytic Enantioselective Michael Addition of 1,3-Dicarbonyl Compounds to Nitroalkenes Catalyzed by Well-Defined Chiral Ru Amido Complexes. Journal of the American Chemical Society 2004 , 126 (36) , 11148-11149. 126 (36) , 11148-11149. https://doi.org/10.1021/ja046296g

Yihui Chen,, Adam Sumlin,, Janet Morgan,, Amy Gryshuk,, Allan Oseroff,, Barbara W. Henderson,, Thomas J. Dougherty, and, Ravindra K. Pandey . Synthesis and Photosensitizing Efficacy of Isomerically Pure Bacteriopurpurinimides. Journal of Medicinal Chemistry 2004 , 47 (20) , 4814-4817. 47 (20) , 4814-4817. https://doi.org/10.1021/jm049630s

Xiaoguang Li,, Xiaofeng Wu,, Weiping Chen,, Fred E. Hancock,, Frank King, and, Jianliang Xiao . Asymmetric Transfer Hydrogenation in Water with a Supported Noyori−Ikariya Catalyst. Organic Letters 2004 , 6 (19) , 3321-3324. 6 (19) , 3321-3324. https://doi.org/10.1021/ol0487175

Stephanie Bastin,, Richard J. Eaves,, Christopher W. Edwards,, Osamu Ichihara,, Mark Whittaker, and, Martin Wills . A Soluble-Polymer System for the Asymmetric Transfer Hydrogenation of Ketones. The Journal of Organic Chemistry 2004 , 69 (16) , 5405-5412. 69 (16) , 5405-5412. https://doi.org/10.1021/jo049479u

Peter Brandt,, Peter Roth, and, Pher G. Andersson . Origin of Enantioselectivity in the Ru(arene)(amino alcohol)-Catalyzed Transfer Hydrogenation of Ketones. The Journal of Organic Chemistry 2004 , 69 (15) , 4885-4890. 69 (15) , 4885-4890. https://doi.org/10.1021/jo030378q

Robert J. Nielsen,, Jason M. Keith,, Brian M. Stoltz, and, William A. Goddard, III . A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (−)-Sparteine−PdII Complexes. Journal of the American Chemical Society 2004 , 126 (25) , 7967-7974. 126 (25) , 7967-7974. https://doi.org/10.1021/ja031911m

Jérôme Hannedouche,, Guy J. Clarkson, and, Martin Wills . A New Class of “Tethered” Ruthenium(II) Catalyst for Asymmetric Transfer Hydrogenation Reactions. Journal of the American Chemical Society 2004 , 126 (4) , 986-987. 126 (4) , 986-987. https://doi.org/10.1021/ja0392768

Pei Nian Liu,, Pei Ming Gu,, Fei Wang, and, Yong Qiang Tu . Efficient Heterogeneous Asymmetric Transfer Hydrogenation of Ketones Using Highly Recyclable and Accessible Silica-Immobilized Ru-TsDPEN Catalysts. Organic Letters 2004 , 6 (2) , 169-172. 6 (2) , 169-172. https://doi.org/10.1021/ol036065z

Glynn D. Williams,, Richard A. Pike,, Charles E. Wade, and, Martin Wills . A One-Pot Process for the Enantioselective Synthesis of Amines via Reductive Amination under Transfer Hydrogenation Conditions. Organic Letters 2003 , 5 (22) , 4227-4230. 5 (22) , 4227-4230. https://doi.org/10.1021/ol035746r

Masato Ito,, Makoto Hirakawa,, Akihide Osaku, and, Takao Ikariya . Highly Efficient Chemoselective Hydrogenolysis of Epoxides Catalyzed by a (η5-C5(CH3)5)Ru Complex Bearing a 2-(Diphenylphosphino)ethylamine Ligand. Organometallics 2003 , 22 (21) , 4190-4192. 22 (21) , 4190-4192. https://doi.org/10.1021/om034006j

Jan-Willem Handgraaf,, Joost N. H. Reek, and, Evert Jan Meijer . Iridium(I) versus Ruthenium(II). A Computational Study of the Transition Metal Catalyzed Transfer Hydrogenation of Ketones. Organometallics 2003 , 22 (15) , 3150-3157. 22 (15) , 3150-3157. https://doi.org/10.1021/om030104t

Masahito Watanabe,, Kunihiko Murata, and, Takao Ikariya . Enantioselective Michael Reaction Catalyzed by Well-Defined Chiral Ru Amido Complexes: Isolation and Characterization of the Catalyst Intermediate, Ru Malonato Complex Having a Metal−Carbon Bond. Journal of the American Chemical Society 2003 , 125 (25) , 7508-7509. 125 (25) , 7508-7509. https://doi.org/10.1021/ja035435b

Yaping Ma,, Hui Liu,, Li Chen,, Xin Cui,, Jin Zhu, and, Jingen Deng . Asymmetric Transfer Hydrogenation of Prochiral Ketones in Aqueous Media with New Water-Soluble Chiral Vicinal Diamine as Ligand. Organic Letters 2003 , 5 (12) , 2103-2106. 5 (12) , 2103-2106. https://doi.org/10.1021/ol0345125

Takayuki Hamada,, Takayoshi Torii,, Kunisuke Izawa,, Ryoji Noyori, and, Takao Ikariya . Practical Synthesis of Optically Active Styrene Oxides via Reductive Transformation of 2-Chloroacetophenones with Chiral Rhodium Catalysts. Organic Letters 2002 , 4 (24) , 4373-4376. 4 (24) , 4373-4376. https://doi.org/10.1021/ol020213o

J. W. Faller and, Adrien R. Lavoie . Enantioselective Syntheses of Nonracemic Benzyl-α-d Alcohols via Catalytic Transfer-Hydrogenation with Ru, Os, Rh, and Ir Catalysts. Organometallics 2002 , 21 (16) , 3493-3495. 21 (16) , 3493-3495. https://doi.org/10.1021/om020058h

Takeyuki Suzuki,, Kenji Morita,, Mika Tsuchida, and, Kunio Hiroi . Mild and Chemoselective Synthesis of Lactones from Diols Using a Novel Metal−Ligand Bifunctional Catalyst. Organic Letters 2002 , 4 (14) , 2361-2363. 4 (14) , 2361-2363. https://doi.org/10.1021/ol026091h

Masahito Watanabe,, Kunihiko Murata, and, Takao Ikariya . Practical Synthesis of Optically Active Amino Alcohols via Asymmetric Transfer Hydrogenation of Functionalized Aromatic Ketones. The Journal of Organic Chemistry 2002 , 67 (5) , 1712-1715. 67 (5) , 1712-1715. https://doi.org/10.1021/jo011076w

Kunihiko Murata,, Hirokazu Konishi,, Masato Ito, and, Takao Ikariya . Deprotonation of Organic Compounds Bearing Acid Protons Promoted by Metal Amido Complexes with Chiral Diamine Ligands Leading to New Organometallic Compounds. Organometallics 2002 , 21 (2) , 253-255. 21 (2) , 253-255. https://doi.org/10.1021/om010874+

Ryoji Noyori,, Masashi Yamakawa, and, Shohei Hashiguchi . Metal−Ligand Bifunctional Catalysis: A Nonclassical Mechanism for Asymmetric Hydrogen Transfer between Alcohols and Carbonyl Compounds. The Journal of Organic Chemistry 2001 , 66 (24) , 7931-7944. 66 (24) , 7931-7944. https://doi.org/10.1021/jo010721w

Chul-Ho Jun,, Dae-Yon Lee,, Yeon-Hee Kim, and, Hyuk Lee . Catalytic Carbon−Carbon Bond Activation of sec-Alcohols by a Rhodium(I) Complex. Organometallics 2001 , 20 (13) , 2928-2931. 20 (13) , 2928-2931. https://doi.org/10.1021/om010087c

Vincent Guiral,, Françoise Delbecq, and, Philippe Sautet . Origin of the Enantioselectivity in the Hydrogen Transfer Reduction of Carbonyls by a Rhodium(I) Complex: A Theoretical Study. Organometallics 2001 , 20 (11) , 2207-2214. 20 (11) , 2207-2214. https://doi.org/10.1021/om010120v

Masato Ito,, Makoto Hirakawa,, Kunihiko Murata, and, Takao Ikariya . Hydrogenation of Aromatic Ketones Catalyzed by (η5-C5(CH3)5)Ru Complexes Bearing Primary Amines. Organometallics 2001 , 20 (3) , 379-381. 20 (3) , 379-381. https://doi.org/10.1021/om000912+

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