NASA's New Horizons spacecraft captured this high-resolution, enhanced color view of Pluto’s largest moon, Charon, just before closest approach on July 14, 2015. The image combines blue, red and infrared images taken by the spacecraft's Ralph/Multispectral Visual Imaging Camera (MVIC); the colors are processed to best highlight the variation of surface properties across Charon. Scientists have learned that reddish material in the north (top) polar region – informally named Mordor Macula – is chemically processed methane that escaped from Pluto’s atmosphere onto Charon. Charon is 754 miles (1,214 kilometers) across; this image resolves details as small as 1.8 miles (2.9 kilometers). Credit: NASA/JHUAPL/SwRI

In June 2015, when the cameras on NASA's approaching New Horizons spacecraft first spotted the large reddish polar region on Pluto's largest moon, Charon, mission scientists knew two things: they'd never seen anything like it elsewhere in our solar system, and they couldn't wait to get the story behind it.

Over the past year, after analyzing the images and other data that New Horizons has sent back from its historic July 2015 flight through the Pluto system, the scientists think they've solved the mystery. As they detail this week in the international scientific journal Nature, Charon's polar coloring comes from Pluto itself – as methane gas that escapes from Pluto's atmosphere and becomes "trapped" by the moon's gravity and freezes to the cold, icy surface at Charon's pole. This is followed by chemical processing by ultraviolet light from the sun that transforms the methane into heavier hydrocarbons and eventually into reddish organic materials called tholins.

"Who would have thought that Pluto is a graffiti artist, spray-painting its companion with a reddish stain that covers an area the size of New Mexico?" asked Will Grundy, a New Horizons co-investigator from Lowell Observatory in Flagstaff, Arizona, and lead author of the paper. "Every time we explore, we find surprises. Nature is amazingly inventive in using the basic laws of physics and chemistry to create spectacular landscapes."

The team combined analyses from detailed Charon images obtained by New Horizons with computer models of how ice evolves on Charon's poles. Mission scientists had previously speculated that methane from Pluto's atmosphere was trapped in Charon's north pole and slowly converted into the reddish material, but had no models to support that theory.

The New Horizons team dug into the data to determine whether conditions on the Texas-sized moon (with a diameter of 753 miles or 1,212 kilometers) could allow the capture and processing of methane gas. The models using Pluto and Charon's 248-year orbit around the sun show some extreme weather at Charon's poles, where 100 years of continuous sunlight alternate with another century of continuous darkness. Surface temperatures during these long winters dip to -430 Fahrenheit (-257 Celsius), cold enough to freeze methane gas into a solid.

"The methane molecules bounce around on Charon's surface until they either escape back into space or land on the cold pole, where they freeze solid, forming a thin coating of methane ice that lasts until sunlight comes back in the spring," Grundy said. But while the methane ice quickly sublimates away, the heavier hydrocarbons created from it remain on the surface.

The models also suggested that in Charon's springtime the returning sunlight triggers conversion of the frozen methane back into gas. But while the methane ice quickly sublimates away, the heavier hydrocarbons created from this evaporative process remain on the surface.

Sunlight further irradiates those leftovers into reddish material – called tholins – that has slowly accumulated on Charon's poles over millions of years. New Horizons' observations of Charon's other pole, currently in winter darkness – and seen by New Horizons only by light reflecting from Pluto, or "Pluto-shine" – confirmed that the same activity was occurring at both poles.

"This study solves one of the greatest mysteries we found on Charon, Pluto's giant moon," said Alan Stern, New Horizons principal investigator from the Southwest Research Institute, and a study co-author. "And it opens up the possibility that other small planets in the Kuiper Belt with moons may create similar, or even more extensive 'atmospheric transfer' features on their moons."

More information: W. M. Grundy et al. The formation of Charon's red poles from seasonally cold-trapped volatiles, Nature (2016). Journal information: Nature W. M. Grundy et al. The formation of Charon's red poles from seasonally cold-trapped volatiles,(2016). DOI: 10.1038/nature19340