An Angel favorite is now hanging with a real devil.

Charisma Carpenter is guest-starring in a Season 2 episode of Fox’s Lucifer, the Buffyverse alumna shared via Twitter. TVLine has since confirmed that Carpenter will be playing Jamie Lee Adrienne, a former Playmate with a lot of party years on her. Married to a once-successful action star, Jamie Lee’s demeanor suggests sadness and pain — or that she is hiding something….

Lucifer returns on Monday, Sept. 19 at 9/8c; Carpenter will appear in the fifth episode.

Previously announced Lucifer Season 2 castings include new series regular Tricia Helfer (playing the fellas’ mother), recurring player Aimee Garcia and Sopranos Emmy winner Michael Imperioli (as the angel Uriel).

Carpenter’s previous TV credits also include Greek, The Lying Game, a Chicago P.D. arc, episodes of Scream Queens and Sons of Anarchy, plus hosting ID’s Surviving Evil.

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