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PITTSBURGH — Police say a Pennsylvania man shot and killed a woman just moments after she rejected his advances at a bar.

Charles McKinney is accused of killing 29-year-old Janese Talton outside a Pittsburgh bar early Friday. Talton is the sister of Pittsburgh Democratic state Rep. Ed Gainey.

Police say McKinney led authorities on a car chase and was shot after his vehicle nearly hit two officers, then sped toward several others.

The 41-year-old Penn Hills man faces charges including homicide and aggravated assault.