MONDAY, OCTOBER 13“Alive and Kicking” – (8:00-9:00 p.m. ET) (TV-14, V) (HDTV)GUEST STAR NATHANIEL BUZOLIC APPEARS IN FLASHBACKS TO THE 1700s — As tensions between Elijah (Daniel Gillies) and Hayley (Phoebe Tonkin) grow, Klaus (Joseph Morgan) steps in and encourages her to regain her position within her werewolf pack. Still under Davina’s (Danielle Campbell) control, Mikael (Sebastian Roche) grows impatient while she attempts to uncover a spell that would protect those closest to her. When Elijah turns to Marcel (Charles Michael Davis) for help in tracking down a vital piece of information, he is forced to remember a time long ago when they were on better terms. Meanwhile, Davina and Kaleb (guest star Daniel Sharmon) find themselves in a dangerous situation when unexpected visitors show up and crash their dinner. Finally, Klaus grows suspicious after a meeting with Cassie (guest star Natalie Dreyfuss) doesn’t go as he had planned. Jeffrey Hunt directed the episode written by Michelle Paradise & Michael Narducci (#202). Original airdate 10/13/2014.SERIES PREMIERE“Chapter One (Pilot)” – (9:00-10:00 p.m. ET) (TV-14, DL) (HDTV)A NEW ONE-HOUR COMEDY ON THE CW — Jane Villanueva (Gina Rodriguez) is a driven young woman studying to become a teacher, nursing a dream to be a writer, and supporting herself with a job at a hot new Miami hotel. All the years of watching telenovelas with the two women who raised her – her sexy, young-at-heart mother, Xiomara (Andrea Navedo) and her still-devout grandmother, Alba (Ivonne Coll) – have given Jane a slightly unrealistic view of romance, but her wonderful fiancé, Michael (Brett Dier), is supportive and even understands her decision to “save herself” until marriage. All of Jane’s meticulous life plans are turned upside down, however, when she sees her doctor for a routine check-up and is accidentally artificially inseminated with a specimen meant for someone else. Now, Jane is faced with the most important decisions of her life – a life that has suddenly become as dramatic, complicated and unpredictable as the telenovelas she has always loved. Justin Baldoni, Jaime Camil and Yael Grobglas also star. Brad Siberling directed the episode written by Jennie Snyder Urman (#101). Original airdate 10/13/2014TUESDAY, OCTOBER 14“Fastest Man Alive” – (8:00-9:00 p.m. ET) (TV-PG, LV) (HDTV)BARRY HAS FUN WITH HIS NEW POWERS BUT A SETBACK MAKES HIM QUESTION HIS ABILITY TO BE A HERO — Barry (Grant Gustin) escorts Iris (Candice Patton) to a university gathering honoring scientist Simon Stagg (guest star William Sadler). When six gunmen storm the event, Barry changes into The Flash and tries to stop them. While he does save a man’s life, he passes out before he can capture the robbers, which frustrates him. As Dr. Wells (Tom Cavanagh), Caitlin (Danielle Panabaker) and Cisco (Carlos Valdes) scramble to find out what’s wrong with Barry, Joe (Jesse Martin) comes down hard on Barry for taking the law into his own hands and risking his life. Barry realizes that it wasn’t six gunmen but a metahuman named Danton Black (guest star Michael Christopher Smith), who can make multiples of himself. Meanwhile, Iris becomes even more intrigued by the “red streak.” David Nutter directed the episode with story by Greg Berlanti & Andrew Kreisberg and teleplay by Andrew Kreisberg & Geoff Johns (101). Original airdate 10/14/2014.“Reichenbach” – (9:00-10:00 p.m. ET) (TV-14, DLV) (HDTV)CROWLEY TELLS DEAN THE MARK NEEDS TO BE FED — Crowley (Mark Sheppard) notices Dean (Jensen Ackles) is becoming more and more aggressive. Dean tells him that’s the side effect of being a demon, but Crowley knows it’s something more - the Mark of Cain needs to be fed. Meanwhile, Sam (Jared Padalecki) is captured by Cole (guest star Travis Aaron Wade), an angry man who blames Dean for his father’s death years ago and wants revenge. Cole tortures Sam, hoping he’ll tell him where Dean is hiding. Hannah (guest star Erica Carroll) sees how weak Castiel (Misha Collins) is becoming as his grace continues to fade, so she makes a bold choice and asks Metatron (guest star Curtis Armstrong) for help. Thomas J. Wright directed the episode written by Andrew Dabb (#1003). Original airdate 10/14/2014.WEDNESDAY, OCTOBER 15“Sara” — (8:00-9:00 p.m. ET) (TV-14, DLV) (HDTV)COLIN DONNELL RETURNS AS TOMMY MERLYN IN A FLASHBACK; MATT WARD GUEST STARS AS SIMON LACROIX, AKA KOMODO — Lance (Paul Blackthorne) calls the Arrow (Stephen Amell) when another archer appears in town and starts skewering businessmen. Diggle (David Ramsey) uses A.R.G.U.S. to find the archer’s identity; he is a man named Simon Lacroix (guest star Matt Ward), who goes by the codename Komodo. However, the team hits a rough patch with the mission and gets help from a surprising source – Laurel (Katie Cassidy). Meanwhile, Oliver begins to worry that he hasn’t heard from Thea (Willa Holland), which forces Roy (Colton Haynes) to tell him the truth about why she left town. Ray Palmer (Brandon Routh) pursues Felicity (Emily Bett Rickards). In the flashback, Maseo (guest star Karl Yune) tells Oliver that Amanda Waller has ordered his first kill. As Oliver looks down the scope of the rifle, he sees the target is his best friend, Tommy (guest star Colin Donnell). Despite her promise to her sister, Laurel debates sharing a secret about Sara (Caity Lotz) with Lance. Wendey Stanzler directed the episode written by Jake Coburn & Keto Shimizu (#302). Original airdate 10/15/2014.“Fastest Man Alive” – (9:00-10:00 p.m. ET) (TV-PG, LV) (HDTV)BARRY HAS FUN WITH HIS NEW POWERS BUT A SETBACK MAKES HIM QUESTION HIS ABILITY TO BE A HERO — Barry (Grant Gustin) escorts Iris (Candice Patton) to a university gathering honoring scientist Simon Stagg (guest star William Sadler). When six gunmen storm the event, Barry changes into The Flash and tries to stop them. While he does save a man’s life, he passes out before he can capture the robbers, which frustrates him. As Dr. Wells (Tom Cavanagh), Caitlin (Danielle Panabaker) and Cisco (Carlos Valdes) scramble to find out what’s wrong with Barry, Joe (Jesse Martin) comes down hard on Barry for taking the law into his own hands and risking his life. Barry realizes that it wasn’t six gunmen but a metahuman named Danton Black (guest star Michael Christopher Smith), who can make multiples of himself. Meanwhile, Iris becomes even more intrigued by the “red streak.” David Nutter directed the episode with story by Greg Berlanti & Andrew Kreisberg and teleplay by Andrew Kreisberg & Geoff Johns (101). Original airdate 10/14/2014.THURSDAY, OCTOBER 16“Welcome to Paradise” – (8:00-9:00 p.m. ET) (TV-14, LV) (HDTV)TROUBLE AT THE SWIMMING HOLE — In an attempt to bring some fun back into their lives, Elena (Nina Dobrev) persuades Caroline (Candice Accola) to meet her at the swimming hole where she plans to introduce her to Liam (guest star Marco James). Tyler (Michael Trevino), still working on controlling his anger issues, asks Liv (guest star Penelope Mitchell) for a favor and is surprised when she makes an unexpected confession. Stefan (Paul Wesley) arrives back in Mystic Falls looking for Enzo (Michael Malarkey) and is caught off guard when he notices a strange change in Elena. Meanwhile, at the lake, Enzo’s actions cause Matt (Zach Roerig) to make a startling revelation, and Jeremy makes a discovery about the anti-magic spell that could potentially put Elena’s life in danger. Elsewhere, Damon (Ian Somerhalder) and Bonnie (Kat Graham) stumble upon clues that lead them to believe they’re not alone. Michael Allowitz directed the episode written by Brian Young (#603). Original airdate 10/16/2014.“Coronation” – (9:00-10:00 p.m. ET) (TV-14, SV) (HDTV)MARY OVERSTEPS HER BOUNDS — With France in a state of famine, as well as religious and political unrest, Mary (Adelaide Kane) looks for a way to feed the people, risking the wrath of a vengeful Lord Narcisse (guest star Craig Parker). Francis (Toby Regbo) is preoccupied by the harrowing suspicion that his dead father’s spirit can possess the living and is haunting Francis as revenge for his murder. As Catherine (Megan Follows) makes excessive and lavish preparations for a coronation ceremony to give the impression of stability to the realm, Bash (Torrance Coombs) confronts the reality of a country plagued by fear, bankruptcy, and murder. Anna Popplewell, Celina Sinden, Caitlin Stasey, Jonathan Keltz and Sean Teale also star. Holly Dale directed the episode written by Harley Peyton (#203). Original airdate 10/16/2014.FRIDAY, OCTOBER 17“Chapter One (Pilot)” – (8:00-9:00 p.m. ET) (TV-14, DL) (HDTV)A NEW ONE-HOUR COMEDY ON THE CW — Jane Villanueva (Gina Rodriguez) is a driven young woman studying to become a teacher, nursing a dream to be a writer, and supporting herself with a job at a hot new Miami hotel. All the years of watching telenovelas with the two women who raised her – her sexy, young-at-heart mother, Xiomara (Andrea Navedo) and her still-devout grandmother, Alba (Ivonne Coll) – have given Jane a slightly unrealistic view of romance, but her wonderful fiancé, Michael (Brett Dier), is supportive and even understands her decision to “save herself” until marriage. All of Jane’s meticulous life plans are turned upside down, however, when she sees her doctor for a routine check-up and is accidentally artificially inseminated with a specimen meant for someone else. Now, Jane is faced with the most important decisions of her life – a life that has suddenly become as dramatic, complicated and unpredictable as the telenovelas she has always loved. Justin Baldoni, Jaime Camil and Yael Grobglas also star. Brad Siberling directed the episode written by Jennie Snyder Urman (#101). Original airdate 10/13/2014