As methane concentrations increase in the Earth’s atmosphere, chemical fingerprints point to a probable source: shale oil and gas, according to new Cornell research published Aug. 14 in Biogeosciences, a journal of the European Geosciences Union.

Natural gas storage tanks near the Haynesville shale formation in Texas receive gas before getting transported via high-pressure pipeline. Photo on the left was taken with a normal camera and the seeping methane is invisible. The photo on the right was taken with an infrared camera, tuned to the methane infrared spectrum – allowing for the visualization of the seeping gas.

The research suggests that this methane has less carbon-13 relative to carbon-12 (denoting the weight of the carbon atom at the center of the methane molecule) than does methane from conventional natural gas and other fossil fuels such as coal.

This carbon-13 signature means that since the use of high-volume hydraulic fracturing – commonly called fracking – shale gas has increased in its share of global natural gas production and has released more methane into the atmosphere, according to the paper’s author, Robert Howarth, the David R. Atkinson Professor of Ecology and Environmental Biology at Cornell.

About two-thirds of all new gas production over the last decade has been shale gas produced in the United States and Canada, he said.

While atmospheric methane concentrations have been rising since 2008, the carbon composition of the methane has also changed. Methane from biological sources such as cows and wetlands have a low carbon-13 content – compared to methane from most fossil fuels. Previous studies erroneously concluded that biological sources are the cause of the rising methane, Howarth said.

Carbon dioxide and methane are critical greenhouse gases, but they behave quite differently in the atmosphere. Carbon dioxide emitted today will influence the climate for centuries to come, as the climate responds slowly to decreasing amounts of the gas.

Unlike its slow response to carbon dioxide, the atmosphere responds quickly to changes in methane emissions.

“Reducing methane now can provide an instant way to slow global warming and meet the United Nations’ target of keeping the planet well below a 2-degree Celsius average rise,” Howarth said, referring to the 2015 Paris Agreement that boosts the global response to climate change threats.

Atmospheric methane levels had previously risen during the last two decades of the 20th century but leveled in the first decade of 21st century. Then, atmospheric methane levels increased dramatically from 2008-14, from about 570 teragrams (570 billion tons) annually to about 595 teragrams, due to global human-caused methane emissions in the last 11 years.

“This recent increase in methane in massive,” Howarth said. “It’s globally significant. It’s contributed to some of the increase in global warming we’ve seen and shale gas is a major player.

“If we can stop pouring methane into the atmosphere, it will dissipate,” he said. “It goes away pretty quickly, compared to carbon dioxide. It’s the low-hanging fruit to slow global warming.”

This research was funded by the Park Foundation and the Atkinson Center.