The electronic structure of erbium silicide ultra-thin films epitaxially grown on Si(111) has been studied by means of angle-resolved ultra-violet photoemission spectroscopy (ARUPS) in the coverage range 0.2–4 monolayers (ML). Some peaks probably related to the silicide surface atomic structure are observed at any coverage. Features that appear at normal emission in connection with an R3 superstructure are ascribed to vacancy-induced states in the silicon surface plane. No true interface states could be identified in this study.