The Front Cover picture displays the Keck machine, a 3D mass spectrum used for identification, and the silylketene molecule in front of a computer‐generated image mimicking an interstellar object (provided by Gerd Altmann) in the background. More information can be found in the Full Paper by G. Tarczay, R. I. Kaiser, and co‐workers on page 882 in Issue 8, 2017 (DOI: 10.1002/cphc.201601422).