Left: The surface of Rosetta’s comet. As the comet approaches the Sun, frozen gases evaporate from below the surface, dragging tiny particles of dust along with them. Right: These dust grains can be captured and examined using the COSIMA instrument. Targets such as this one measuring only a few centimeters act as dust collectors. They retain dust particles of up to 100 microns in size. Credit: ESA/Rosetta/MPS for OSIRIS Team MPS/UPD/LAM/IAA/SSO/INTA/UPM/DASP/IDA (left), ESA / Rosetta / MPS for COSIMA Team MPS / CSNSM / UNIBW / TUORLA / IWF / IAS / ESA / BUW / MPE / LPC2E / LCM / IMF / UTU / LISA / UOFC / vH & S. (right)

The dust that comet 67P/Churyumov-Gerasimenko emits into space consists to about one half of organic molecules. The dust belongs to the most pristine and carbon-rich material known in our solar system and has hardly changed since its birth. These results of the COSIMA team are published today in the journal Monthly Notices of the Royal Astronomical Society. COSIMA is an instrument onboard the Rosetta spacecraft, which investigated comet 67P/Churyumov-Gerasimenko from August 2014 to September 2016. In their current study, the involved researchers including scientists from the Max Planck Institute for Solar System Research (MPS) analyze as comprehensively as ever before, what chemical elements constitute cometary dust.

When a comet traveling along it highly elliptical orbit approaches the Sun, it becomes active: frozen gases evaporate, dragging tiny dust grains into space. Capturing and examining these grains provides the opportunity to trace the "building materials" of the comet itself. So far, only few space missions have succeeded in this endeavor. These include ESA's Rosetta mission. Unlike their predecessors, for their current study the Rosetta researchers were able to collect and analyze dust particles of various sizes over a period of approximately two years. In comparison, earlier missions, such as Giotto's Flyby of comet 1P/Halley or Stardust, which even returned cometary dust from comet 81P/Wild 2 back to Earth, provided only a snapshot. In the case of the space probe Stardust, which raced past its comet in 2004, the dust had changed significantly during capture, so that a quantitative analysis was only possible to a limited extent.

In the course of the Rosetta mission, COSIMA collected more than 35000 dust grains. The smallest of them measured only 0.01 millimeters in diameter, the largest about one millimeter. The instrument makes it possible to first observe the individual dust grains with a microscope. In a second step, these grains are bombarded with a high-energy beam of indium ions. The secondary ions emitted in this way can then be "weighed" and analyzed in the COSIMA mass spectrometer. For the current study, the researchers limited themselves to 30 dust grains with properties that ensured a meaningful analysis. Their selection includes dust grains from all phases of the Rosetta mission and of all sizes.

"Our analyzes show that the composition of all these grains is very similar," MPS researcher Dr. Martin Hilchenbach, Principal Investigator of the COSIMA team, describes the results. The scientists conclude that the comet's dust consists of the same "ingredients" as the comet's nucleus and thus can be examined in its place.

Left: Overview of the chemical elements that make up Rosetta’s comet. Right: Average mass distribution of organic and mineral substances in Rosetta’s comet. Credit: © ESA / Rosetta / MPS for COSIMA Team MPS / CSNSM / UNIBW / TUORLA / IWF / IAS / ESA / BUW / MPE / LPC2E / LCM / IMF / UTU / LISA / UOFC / vH & S.

As the study shows, organic molecules are among those ingredients at the top of the list. These account for about 45 percent of the weight of the solid cometary material. "Rosetta's comet thus belongs to the most carbon-rich bodies we know in the solar system," says MPS scientist and COSIMA team member Dr. Oliver Stenzel. The other part of the total weight, about 55 percent, is provided by mineral substances, mainly silicates. It is striking that they are almost exclusively non-hydrated minerals i.e. missing water compounds.

"Of course, Rosetta's comet contains water like any other comet, too," says Hilchenbach. "But because comets have spent most of their time at the icy rim of the solar system, it has almost always been frozen and could not react with the minerals." The researchers therefore regard the lack of hydrated minerals in the comet's dust as an indication that 67P contains very pristine material.

This conclusion is supported by the ratio of certain elements such as carbon to silicon. With more than 5, this value is very close to the Sun's value, which is thought to reflect the ratio found in the early solar system.

The current findings also touch on our ideas of how life on Earth came about. In a previous publication, the COSIMA team was able to show that the carbon found in Rosetta's comet is mainly in the form of large, organic macromolecules. Together with the current study, it becomes clear that these compounds make up a large part of the cometary material. Thus, if comets indeed supplied the early Earth with organic matter, as many researchers assume, it would probably have been mainly in the form of such macromolecules.

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