In the first experiments able to mimic the crushing, searing conditions found in Earth's lower mantle, and simultaneously probe tell-tale properties of iron, scientists* have discovered that material there behaves very differently than predicted by models. The research also points to the likelihood of a new zone deep in the Earth.

Surface phenomena such as volcanoes and earthquakes are generated by what goes on in Earth's interior. To understand some of these surface dynamics, scientists have to probe deep into the planet. The lower mantle is between 400 and 1,740 miles deep (650 km- 2,800 km) and sits atop the outer core.

Coauthor of the paper, Viktor Struzhkin of the Carnegie Institution's Geophysical Laboratory explains: "The deeper you go, the higher the pressures and temperatures become. Under these extreme conditions, the atoms and electrons of the rocks become squeezed so close together that they interact very peculiarly. In fact, spinning electrons in iron, which is prevalent throughout the inner Earth, are forced to pair up. When this spin state changes from unpaired electrons--called a high-spin state--to paired electrons--a low-spin state--the density, sound velocities, conductivity, and other properties of the materials can change. Understanding these conditions helps scientists piece together the complex puzzle of the interior/surface interactions."

The pressures in the lower mantle are brutal, ranging from about 230,000 times the atmospheric pressure at sea level (23 GPa), to almost 1.35 million times sea-level pressure (135 GPa). The heat is equally extreme--from about 2,800 to 6,700 degrees Fahrenheit (1800 K--4000 K).

Using a laser-heated diamond anvil cell to heat and compress the samples, the scientists subjected ferropericlase to almost 940,000 atmospheres and 3,140 °F. They analyzed it using so-called X-ray emission spectroscopy. As its name suggests, ferropericlase is iron-laden.

It is also the second most prevalent material found in the lower mantle. Previous to this study, ferropericlase has been subjected to high pressures, but only to room temperatures. The new experiments are the highest pressures and temperatures attained to probe the spin state of iron in the mineral at lower-mantle conditions.

Under the less-intense conditions of the former experiments, the high-spin to low-spin transition occurs in a narrow pressure range. In the new study, however, both spin states coexisted in the same crystal structure and the spin transition was also continuous over a large pressure range, indicating that the mineral is in a complex state over a large range in depth in the planet.

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"We were expecting to find a transition zone, but did not know how extended it may be in the Earth's mantle," commented Struzhkin. "Our findings suggest that there is a region or 'spin-transition zone' from about 620 miles to 1,365 miles deep, where high spin, unpaired electrons, transition to low spin, paired electrons. The transitioning appears to be continuous over these depths. At pressures representing a lower depth of about 1,365 miles the transition stops and ferropericlase is dominated by low-spin electrons."

Since measurements that scientists use to determine the composition and density of the inner Earth, such as sound velocities, are influenced by the ratio of high-spin/low- spin states, the new finding calls into question the traditional techniques for modeling this region of the planet.

In addition, a continuous spin transition zone may explain some interesting experimental findings including why there has been no significant iron partitioning, or separating, into ferropericlase or perovskite, the most prevalent mineral in the region. The research also suggests that the depth of the transition zone is less than scientists had speculated.

The existence of this transition zone may also account for seismic-wave behavior at those depths. The fact that the lowermost area is dominated by denser low-spin material could also affect the temperature stability of mantle upwellings--the generators of volcanic hotspots, such as those in Hawaii.

"This paper solves only part of the puzzle," cautioned Struzhkin. "Since the major lower mantle mineral perovskite has not been measured yet with this technique, we know there are more surprises to come."

"The spin transition zone of iron needs to be considered in future models of the lower mantle," said Choong-Shik Yoo, a former staff member at LLNL and now a professor at Washington State University. "In the past, geophysicists had neglected the effects of the spin transition when studying the Earth's interior.

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Since we identified this zone, the next step is to study the properties of lower mantle oxides and silicates across the zone. This research also calls for future seismic and geodynamic tests in order to understand the properties of the spin transition zone."

"The benchmark techniques developed here have profound implications for understanding the electronic transitions in lanthanoid and actinoid compounds under extreme conditions because their properties would be affected by the electronic transitions," said Valentin Iota, a staff member in LLNL's Physics and Advanced Technologies Directorate.

The work is published in the September 21, 2007, issue of Science.

*Authors on this paper are Jung-Fu Lin, Lawrence Livermore National Laboratory (LLNL); György Vankó, KFKI Research Institute for Particle and Nuclear Physics and the European Synchrotron Radiation Facility; Steven Jacobsen, Northwestern University; Viktor Struzhkin, Carnegie Institution's Geophysical Laboratory; Vitali Prakapenka, University of Chicago; Alexie Kuznetsov, University of Chicago; and Choong-Shik Yoo LLNL.