This water was contaminated by fracking operations in Pennsylvania. Melanie Blanding

Hydraulic fracturing, or fracking, extracts oil and gas from deep underground by injecting water into the ground and breaking the rocks in which the valuable hydrocarbons are trapped. But it also produces wastewater high in certain contaminants — and which may be radioactive.



In a study published Wednesday in the journal Environmental Science and Technology, researchers found high levels of radioactivity, salts and metals in the water and sediments downstream from a fracking wastewater plant on Blacklick Creek in western Pennsylvania.

Among the most alarming findings was that downstream river sediments contain 200 times more radium than mud that's naturally present upstream of the plant, said Avner Vengosh, a co-author of the study and a professor of geochemistry and water quality at Duke University. Radium is a radioactive metal naturally found in many rocks; long-term exposure to large amounts of radium can cause adverse health effects and even diseases such as leukemia. [5 Everyday Things that Are Radioactive]

Contaminated waters

The concentrations of radium Vengosh and his team detected are higher than those found in some radioactive waste dumps, and exceed the minimum threshold the federal government uses to qualify a disposal site as a radioactive dump site, Vengosh told LiveScience. While the Josephine Brine Treatment Facility removes some of the radium from the wastewater, the metal accumulates in the sediment, at dangerously high levels, he added.

Radium can make its way into the food chain by first accumulating in insects and small animals, and then moving on to larger animals, like fish, when they consume the insects and smaller animals, Vengosh added. But it's not known to what extent this is happening, since this study didn't address that question, he said.



For two years, the team monitored sediments and river water above and below the treatment plant, as well as the discharge coming directly from the plant, for various contaminants and levels of radioactivity. In the discharge and downstream water, researchers found high levels of chloride, sulfate and bromide.

Plants that treat oil and gas wastewater are shown in red. The Josephine water treatment plant is shown in black. Warner et al / Environmental Science and Technology

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Levels of salinity in the plant's discharge were up to 200 times higher than what is allowed under the Clean Water Act — and 10 times saltier than ocean water, Vengosh said. But fracking wastewater is exempt from that law, Vengosh said.



The high bromide concentrations that were found were particularly concerning, since bromide can react with chlorine and ozone — which is used to disinfect river water and produce drinking water — to yield highly toxic byproducts. But there's no direct evidence that this has happened yet, Vengosh said.

Several of these contaminants, particularly radium and bromide, may be present in high enough concentrations to cause harm to human health and the environment, but that wasn't addressed in this study, Vengosh said.

'Alarming'

"The occurrence of radium is alarming — this is a radioactive constituent that is likely to increase rates of genetic mutation" and poses "a significant radioactive health hazard for humans," said William Schlesinger, a researcher and president of the Cary Institute of Ecosystem Studies, in Millbrook, N.Y., who wasn't involved in the study.



Researchers say they are sure the contaminants are coming from fracking because the Josephine facility treats this oil and gas wastewater, and the water contains the same chemical signature as rocks in the Marcellus Shale Formation, Vengosh said. This wastewater is often called "flowback," as it's the water that flows back to the surface from underground after being injected into rocks in the fracking process.

In Pennsylvania, some of this water is transported by oil and gas companies to treatment locations such as the Josephine facility, where it is processed and released into streams and rivers. However, much of the water used in fracking is treated by oil and gas companies and reused, or injected into deep wells, said Lisa Kasianowitz, an information specialist at the Pennsylvania Department of Environmental Protection (DEP).

The treatment facility did remove some contaminants, including some of the radium, though enough made it through to accumulate in high levels in sediments, Vengosh said. It also "did nothing" to remove certain salts, like bromide, he said. Traditional wastewater plants are not built to remove these contaminants, he added.

The study "really seals the verdict that it's flowback waters that are contaminating the streams," Schlesinger told LiveScience.

The Pennsylvania DEP confirmed that the Josephine facility is accepting and discharging "conventional oil and gas wastewater in accordance with all applicable laws and regulations," Kasianowitz said.

Vengosh said that the research suggests that similar contamination may be happening in locations with discharge of fracking wastewater throughout the Marcellus Shale formation, which underlies parts of Pennsylvania, New York and Ohio.

Update for 4 p.m. ET Oct. 3: Energy in Depth's Katie Brown has posted a response to the water analysis study— pointing out, among other things, that members of the Marcellus Shale Coalition stopped using the Josephine Brine Treatment Facility in May 2011, that some samples were taken close to the discharge source, and that the levels of radioactivity were well below industrial discharge limits.

In addition to Vengosh, the authors of "Impacts of Shale Gas Wastewater Disposal on Water Quality in Western Pennsylvania" include Nathaniel Warner, Cidney Christie and Robert Jackson. The authors acknowledged funding from Fred and Alice Stanback and the Park Foundation to the Duke University Nicholas School of the Environment. Energy in Depth was launched in 2009 by the Independent Petroleum Association of America.

Email Douglas Main or follow him on Twitter or Google+. Follow us @livescience, Facebook or Google+. Article originally on LiveScience.



