Elements and Atoms: Chapter 3

Lavoisier's Elements of Chemistry

Traité Élementaire de Chimie

Lavoisier was a public servant as well as a scientist. Under the French monarchy, he was a member of the tax-collecting agency, the Ferme Générale. His work for the government included advocating rational agricultural methods and improving the manufacture of gunpowder. His service to France continued during the Revolution. He was an alternate deputy of the reconvened Estates-General in 1789, and from 1790 served on a commission charged with making weights and measures uniform across France. A Parisian by birth, Lavoisier also died in Paris, guillotined with other former members of the Ferme Générale during the Reign of Terror in May 1794.

The preface to his Traité Élementaire de Chimie is a fitting selection to follow Boyle's The Sceptical Chymist because it includes the definition of element that was to dominate chemistry throughout the next century, and which is still familiar in our own day. In addition, Lavoisier's musings on the connection between science and the language which conveys its ideas remain thought-provoking, particularly in light of the writings of Bertrand Russell, Ludwig Wittgenstein, and Alfred Ayer in the first half of the 20 th century. Even his comments about the pedagogy of introductory chemistry take sides in a debate that remains current.

Antoine Lavoisier, Preface to Elements of Chemistry

When I began the following Work, my only object was to extend and explain more fully the Memoir which I read at the public meeting of the Academy of Science in the month of April 1787, on the necessity of reforming and completing the Nomenclature of Chemistry[1]. While engaged in this employment, I perceived, better than I had ever done before, the justice of the following maxims of the Abbé de Condillac[2], in his System of Logic, and some other of his works.

"We think only through the medium of words. --Languages are true analytical methods. --Algebra, which is adapted to its purpose in every species of expression, in the most simple, most exact, and best manner possible, is at the same time a language and an analytical method. --The art of reasoning is nothing more than a language well arranged."

Thus, while I thought myself employed only in forming a Nomenclature, and while I proposed to myself nothing more than to improve the chemical language, my work transformed itself by degrees, without my being able to prevent it, into a treatise upon the Elements of Chemistry.

The impossibility of separating the nomenclature of a science from the science itself, is owing to this, that every branch of physical science must consist of three things; the series of facts which are the objects of the science, the ideas which represent these facts, and the words by which these ideas are expressed. Like three impressions of the same seal, the word ought to produce the idea, and the idea to be a picture of the fact. And, as ideas are preserved and communicated by means of words, it necessarily follows that we cannot improve the language of any science without at the same time improving the science itself; neither can we, on the other hand, improve a science, without improving the language or nomenclature which belongs to it. However certain the facts of any science may be, and, however just the ideas we may have formed of these facts, we can only communicate false impressions to others, while we want words by which these may be properly expressed.[3]

To those who will consider it with attention, the first part of this treatise will afford frequent proofs of the truth of the above observations. But as, in the conduct of my work, I have been obliged to observe an order of arrangement essentially differing from what has been adopted in any other chemical work yet published, it is proper that I should explain the motives which have led me to do so.

It is a maxim universally admitted in geometry, and indeed in every branch of knowledge, that, in the progress of investigation, we should proceed from known facts to what is unknown. In early infancy, our ideas spring from our wants; the sensation of want excites the idea of the object by which it is to be gratified. In this manner, from a series of sensations, observations, and analyses, a successive train of ideas arises, so linked together, that an attentive observer may trace back to a certain point the order and connection of the whole sum of human knowledge.

When we begin the study of any science, we are in a situation, respecting that science, similar to that of children; and the course by which we have to advance is precisely the same which Nature follows in the formation of their ideas. In a child, the idea is merely an effect produced by a sensation; and, in the same manner, in commencing the study of a physical science, we ought to form no idea but what is a necessary consequence, and immediate effect, of an experiment or observation.[4] Besides, he that enters upon the career of science, is in a less advantageous situation than a child who is acquiring his first ideas. To the child, Nature gives various means of rectifying any mistakes he may commit respecting the salutary or hurtful qualities of the objects which surround him. On every occasion his judgments are corrected by experience; want and pain are the necessary consequences arising from false judgment; gratification and pleasure are produced by judging aright. Under such masters, we cannot fail to become well informed; and we soon learn to reason justly, when want and pain are the necessary consequences of a contrary conduct.[5]

In the study and practice of the sciences it is quite different; the false judgments we form neither affect our existence nor our welfare; and we are not forced by any physical necessity to correct them. Imagination, on the contrary, which is ever wandering beyond the bounds of truth, joined to self-love and that self-confidence we are so apt to indulge, prompt us to draw conclusions which are not immediately derived from facts; so that we become in some measure interested in deceiving ourselves. Hence it is by no means to be wondered, that, in the science of physics in general, men have often made suppositions, instead of forming conclusions. These suppositions, handed down from one age to another, acquire additional weight from the authorities by which they are supported, till at last they are received, even by men of genius, as fundamental truths.

The only method of preventing such errors from taking place, and of correcting them when formed, is to restrain and simplify our reasoning as much as possible. This depends entirely upon ourselves, and the neglect of it is the only source of our mistakes. We must trust to nothing but facts: These are presented to us by Nature, and cannot deceive. We ought, in every instance, to submit our reasoning to the test of experiment, and never to search for truth but by the natural road of experiment and observation. Thus mathematicians obtain the solution of a problem by the mere arrangement of data, and by reducing their reasoning to such simple steps, to conclusions so very obvious, as never to lose sight of the evidence which guides them.[6]

Thoroughly convinced of these truths, I have imposed upon myself, as a law, never to advance but from what is known to what is unknown; never to form any conclusion which is not an immediate consequence necessarily flowing from observation and experiment; and always to arrange the fact, and the conclusions which are drawn from them, in such an order as shall render it most easy for beginners in the study of chemistry thoroughly to understand them. Hence I have been obliged to depart from the usual order of courses of lectures and of treatises upon chemistry, which always assume the first principles of the science, as known, when the pupil or the reader should never be supposed to know them till they have been explained in subsequent lessons. In almost every instance, these begin by treating of the elements of matter, and by explaining the table of affinities[7], without considering, that, in so doing, they must bring the principal phenomena of chemistry into view at the very outset: They make use of terms which have not been defined, and suppose the science to be understood by the very persons they are only beginning to teach.[8] It ought likewise to be considered, that very little of chemistry can be learned in a first course, which is hardly sufficient to make the language of the science familiar to the ears, or the apparatus familiar to the eyes. It is almost impossible to become a chemist in less than three or four years of constant application.

These inconveniencies are occasioned not so much by the nature of the subject, as by the method of teaching it; and, to avoid them, I was chiefly induced to adopt a new arrangement of chemistry, which appeared to me more consonant to the order of Nature. I acknowledge, however, that in thus endeavouring to avoid difficulties of one kind, I have found myself involved in others of a different species, some of which I have not been able to remove; but I am persuaded, that such as remain do not arise from the nature of the order I have adopted, but are rather consequences of the imperfection under which chemistry still labours. This science still has many chasms, which interrupt the series of facts, and often render it extremely difficult to reconcile them with each other: It has not, like the elements of geometry, the advantage of being a complete science, the parts of which are all closely connected together: Its actual progress, however, is so rapid, and the facts, under the modern doctrine, have assumed so happy an arrangement, that we have ground to hope, even in our own times, to see it approach near to the highest state of perfection of which it is susceptible.[9]

The rigorous law from which I have never deviated, of forming no conclusions which are not fully warranted by experiment, and of never supplying the absence of facts, has prevented me from comprehending in this work the branch of chemistry which treats of affinities, although it is perhaps the best calculated of any part of chemistry for being reduced into a completely systematic body. Messrs Geoffroy, Gellert, Bergman, Scheele, De Morveau, Kirwan,[10] and many others, have collected a number of particular facts upon this subject, which only wait for a proper arrangement; but the principal data are still wanting, or, at least, those we have are either not sufficiently defined, or not sufficiently proved, to become the foundation upon which to build so very important a branch of chemistry. This science of affinities, or elective attractions, holds the same place with regard to the other branches of chemistry, as the higher or transcendental geometry does with respect to the simpler and elementary part; and I thought it improper to involve those simple and plain elements, which I flatter myself the greatest part of my readers will easily understand, in the obscurities and difficulties which still attend that other very useful and necessary branch of chemical science.

Perhaps a sentiment of self-love may, without my perceiving it, have given additional force to these reflections. Mr de Morveau is at present engaged in publishing the article Affinity in the Methodical Encyclopedia; and I had more reasons than one to decline entering upon a work in which he is employed.

It will, no doubt, be a matter of surprise, that in a treatise upon the elements of chemistry, there should be no chapter on the constituent and elementary parts of matter; but I shall take occasion, in this place, to remark, that the fondness for reducing all the bodies in nature to three or four elements, proceeds from a prejudice which has descended to us from the Greek Philosophers. The notion of four elements, which, by the variety of their proportions, compose all the known substances in nature, is a mere hypothesis, assumed long before the first principles of experimental philosophy or of chemistry had any existence. In those days, without possessing facts, they framed systems; while we, who have collected facts, seem determined to reject them, when they do not agree with our prejudices. The authority of these fathers of human philosophy still carry great weight, and there is reason to fear that it will even bear hard upon generations yet to come.[11]

It is very remarkable, that, notwithstanding of the number of philosophical chemists who have supported the doctrine of the four elements, there is not one who has not been led by the evidence of facts to admit a greater number of elements into their theory. The first chemists that wrote after the revival of letters, considered sulphur and salt as elementary substances entering into the composition of a great number of substances; hence, instead of four, they admitted the existence of six elements. Beccher assumes the existence of three kinds of earth, from the combination of which, in different proportions, he supposed all the varieties of metallic substances to be produced. Stahl gave a new modification to this system; and succeeding chemists have taken the liberty to make or to imagine changes and additions of a similar nature. All these chemists were carried along by the influence of the genius of the age in which they lived, which contented itself with assertions without proofs; or, at least, often admitted as proofs the slightest degrees of probability, unsupported by that strictly rigorous analysis required by modern philosophy.[12]

All that can be said upon the number and nature of elements is, in my opinion, confined to discussions entirely of a metaphysical nature. The subject only furnishes us with indefinite problems, which may be solved in a thousand different ways, not one of which, in all probability, is consistent with nature. I shall therefore only add upon this subject, that if, by the term elements, we mean to express those simple and indivisible atoms of which matter is composed, it is extremely probable we know nothing at all about them; but, if we apply the term elements, or principles of bodies, to express our idea of the last point which analysis is capable of reaching, we must admit, as elements, all the substances into which we are capable, by any means, to reduce bodies by decomposition.[13] Not that we are entitled to affirm, that these substances we consider as simple may not be compounded of two, or even of a greater number of principles; but, since these principles cannot be separated, or rather since we have not hitherto discovered the means of separating them, they act with regard to us as simple substances, and we ought never to suppose them compounded until experiment and observation has proved them to be so.[14]

The foregoing reflections upon the progress of chemical ideas naturally apply to the words by which these ideas are to be expressed. Guided by the work which, in the year 1787, Messrs de Morveau, Berthollet, de Fourcroy, and I composed upon the Nomenclature of Chemistry, I have endeavoured, as much as possible, to denominate simple bodies by simple terms, and I was naturally led to name these first.[15] It will be recollected, that we were obliged to retain that name of any substance by which it had been long known in the world, and that in two cases only we took the liberty of making alterations; first, in the case of those which were but newly discovered, and had not yet obtained names, or at least which had been known but for a short time, and the names of which had not yet received the sanction of the public; and, secondly, when the names which had been adopted, whether by the ancients or the moderns, appeared to us to express evidently false ideas, when they confounded the substances, to which they were applied, with others possessed of different, or perhaps opposite qualities. We made no scruple, in this case, of substituting other names in their room, and the greatest number of these were borrowed from the Greek language. We endeavoured to frame them in such a manner as to express the most general and the most characteristic quality of the substances; and this was attended with the additional advantage both of assisting the memory of beginners, who find it difficult to remember a new word which has no meaning, and of accustoming them early to admit no word without connecting with it some determinate idea.[16]

To those bodies which are formed by the union of several simple substances we gave new names, compounded in such a manner as the nature of the substances directed; but, as the number of double combinations is already very considerable, the only method by which we could avoid confusion, was to divide them into classes. In the natural order of ideas, the name of the class or genus is that which expresses a quality common to a great number of individuals: The name of the species, on the contrary, expresses a quality peculiar to certain individuals only.[17]

These distinctions are not, as some may imagine, merely metaphysical, but are established by Nature. "A child," says the Abbé de Condillac, "is taught to give the name tree to the first one which is pointed out to him. The next one he sees presents the same idea, and he gives it the same name. This he does likewise to a third and a fourth, till at last the word tree, which he first applied to an individual, comes to be employed by him as the name of a class or a genus, an abstract idea, which comprehends all trees in general. But, when he learns that all trees serve not the same purpose, that they do not all produce the same kind of fruit, he will soon learn to distinguish them by specific and particular names." This is the logic of all the sciences, and is naturally applied of chemistry.

The acids, for example, are compounded of two substances, of the order of those which we consider as simple; the one constitutes acidity, and is common to all acids, and, from this substance, the name of the class or the genus ought to be taken; the other is peculiar to each acid, and distinguishes it from the rest, and from this substance is to be taken the name of the species. But, in the greatest number of acids, the two constituent elements, the acidifying principle, and that which it acidifies, may exist in different proportions, constituting all the possible points of equilibrium or of saturation. This is the case in the sulphuric and the sulphurous acids; and these two states of the same acid we have marked by varying the termination of the specific name.

Metallic substances which have been exposed to the joint action of the air and of fire, lose their metallic lustre, increase in weight, and assume an earthy appearance. In this state, like the acids, they are compounded of a principle which is common to all, and one which is peculiar to each. In the same way, therefore, we have thought proper to class them under a generic name, derived from the common principle; for which purpose, we adopted the term oxyd; and we distinguish them from each other by the particular name of the metal to which each belongs.[18]

Combustible substances, which in acids and metallic oxyds are a specific and particular principle, are capable of becoming, in their turn, common principles of a great number of substances. The sulphurous combinations have been long the only known ones in this kind. Now, however, we know, from the experiments of Messrs Vandermonde, Monge, and Berthollet, that charcoal may be combined with iron, and perhaps with several other metals; and that, from this combination, according to the proportions, may be produced steel, plumbago, &c.[19] We know likewise, from the experiments of M. Pelletier, that phosphorus may be combined with a great number of metallic substances. These different combinations we have classed under generic names taken from the common substance, with a termination which marks this analogy, specifying them by another name taken from that substance which is proper to each.

The nomenclature of bodies compounded of three simple substances was attended with still greater difficulty, not only on account of their number, but, particularly, because we cannot express the nature of their constituent principles without employing more compound names. In the bodies which form this class, such as the neutral salts, for instance, we had to consider, 1st, The acidifying principle, which is common to them all; 2d, The acidifiable principle which constitutes their peculiar acid; 3d, The saline, earthy, or metallic basis, which determines the particular species of salt. Here we derived the name of each class of salts from the name of the acidifiable principle common to all the individuals of that class; and distinguished each species by the name of the saline, earthy, or metallic basis, which is peculiar to it.[20]

A salt, though compounded of the same three principles, may, nevertheless, by the mere difference of their proportion, be in three different states. The nomenclature we have adopted would have been defective, had it not expressed these different states; and this we attained chiefly by changes of termination uniformly applied to the same state of the different salts.

In short, we have advanced so far, that from the name alone may be instantly found what the combustible substance is which enters into any combination; whether that combustible substance be combined with the acidifying principle, and in what proportion; what is the state of the acid; with what basis it is united; whether the saturation be exact, or whether the acid or the basis be in excess.

It may be easily supposed that it was not possible to attain all these different objects without departing, in some instances, from established custom, and adopting terms which at first sight will appear uncouth and barbarous. But we considered that the ear is soon habituated to new words, especially when they are connected with a general and rational system. The names, besides, which were formerly employed, such as powder of algaroth, salt of alembroth, pompholix, phagadenic water, turbith mineral, colcothar, and many others, were neither less barbarous nor less uncommon.[21] It required a great deal of practice, and no small degree of memory, to recollect the substances to which they were applied, much more to recollect the genus of combination to which they belonged. The names of oil of tartar per deliquium, oil of vitriol, butter of arsenic and of antimony, flowers of zinc, &c. were still more improper, because they suggested false ideas: For, in the whole mineral kingdom, and particularly in the metallic class, there exists no such thing as butters, oils, or flowers; and, in short, the substances to which they give these fallacious names, are nothing less than rank poisons.[22]

When we published our essay on the nomenclature of chemistry, we were reproached for having changed the language which was spoken by our masters, which they distinguished by their authority, and handed down to us. But those who reproach us on this account, have forgotten that it was Bergman and Macquer themselves who urged us to make this reformation. In a letter which the learned Professor of Upsal, M. Bergman, wrote, a short time before he died, to M. de Morveau, he bids him spare no improper names; those who are learned, will always be learned, and those who are ignorant will thus learn sooner.[23]

There is an objection to the work which I am going to present to the public, which is perhaps better founded, that I have given no account of the opinion of those who have gone before me; that I have stated only my own opinion, without examining that of others. By this I have been prevented from doing that justice to my associates, and more especially to foreign chemists, which I wished to render them. But I beseech the reader to consider, that, if I had filled an elementary work with a multitude of quotations; if I had allowed myself to enter into long dissertations on the history of the science, and the works of those who have studied it, I must have lost sight of the true object I had in view, and produced a work, the reading of which must have been extremely tiresome to beginners. It is not to the history of the science, or of the human mind, that we are to attend in an elementary treatise:[24] Our only aim ought to be ease and perspicuity, and with the utmost care to keep every thing out of view which might draw aside the attention of the student; it is a road which we should be continually rendering more smooth, and from which we should endeavour to remove every obstacle which can occasion delay. The sciences, from their own nature, present a sufficient number of difficulties, though we add not those which are foreign to them. But, besides this, chemists will easily perceive, that, in the fist part of my work, I make very little use of any experiments but those which were made by myself: If at any time I have adopted, without acknowledgment, the experiments or the opinions of M. Berthollet, M. Fourcroy, M. de la Place, M. Monge, or, in general, of any of those whose principles are the same with my own, it is owing to the circumstance, that frequent intercourse, and the habit of communicating our ideas, our observations, and our way of thinking to each other, has established between us a sort of community of opinions, in which it is often difficult for every one to know his own.[25]

The remarks I have made on the order which I thought myself obliged to follow in the arrangement of proofs and ideas, are to be applied only to the first part of this work. It is the only one which contains the general sum of the doctrine I have adopted, and to which I wished to give a form completely elementary.[26]

The second part is composed chiefly of tables of the nomenclature of the neutral salts. To these I have only added general explanations, the object of which was to point out the most simple processes for obtaining the different kinds of known acids. This part contains nothing which I can call my own, and presents only a very short abridgment of the results of these processes, extracted from the works of different authors.

In the third part, I have given a description, in detail, of all the operations connected with modern chemistry. I have long thought that a work of this kind was much wanted, and I am convinced it will not be without use. The method of performing experiments, and particularly those of modern chemistry, is not so generally known as it ought to be; and had I, in the different memoirs which I have presented to the Academy, been more particular in the detail of the manipulations of my experiments, it is probable I should have made myself better understood, and the science might have made a more rapid progress. The order of the different matters contained in this third part appeared to me to be almost arbitrary; and the only one I have observed was to class together, in each of the chapters of which it is composed, those operations which are most connected with one another. I need hardly mention that this part could not be borrowed from any other work, and that, in the principal articles it contains, I could not derive assistance from any thing but the experiments which I have made myself.

I shall conclude this preface by transcribing, literally, some observations of the Abbé de Condillac, which I think describe, with a good deal of truth, the state of chemistry at a period not far distant from our own. These observations were made on a different subject; but they will not, on this account, have less force, if the application of them be thought just.[27]

"Instead of applying observation to the things we wished to know, we have chosen rather to imagine them. Advancing from one ill founded supposition to another, we have at last bewildered ourselves amidst a multitude of errors. These errors becoming prejudices, are, of course, adopted as principles, and we thus bewilder ourselves more and more. The method, too, by which we conduct our reasonings is as absurd; we abuse words which we do not understand, and call this the art of reasoning. When matters have been brought this length, when errors have been thus accumulated, there is but one remedy by which order can be restored to the faculty of thinking; this is, to forget all that we have learned, to trace back our ideas to their source, to follow the train in which they rise, and, as my Lord Bacon says, to frame the human understanding anew.

"This remedy becomes the more difficult in proportion as we think ourselves more learned. Might it not be thought that works which treated of the sciences with the utmost perspicuity, with great precision and order, must be understood by every body? The fact is, those who have never studied any thing will understand them better than those who have studied a great deal, and especially those who have written a great deal."

At the end of the fifth chapter, the Abbé de Condillac adds: "But, after all, the sciences have made progress, because philosophers have applied themselves with more attention to observe, and have communicated to their language that precision and accuracy which they have employed in their observations: In correcting their language they reason better."

Antoine Lavoisier, Table of Simple Substances in Elements of Chemistry

Simple substances belonging to all the kingdoms of nature, which may be considered as the elements of bodies.

Oxydable[32] and Acidifiable simple Substances not Metallic.

New Names. Correspondent old names. Sulphur The same names. Phosphorus Charcoal Muriatic radical[33] Still unknown. Fluoric radical Boracic radical

Oxydable and Acidifiable simple Metallic Bodies.

New Names. Correspondent Old Names. Antimony Regulus[34] of Antimony. Arsenic " " Arsenic Bismuth " " Bismuth Cobalt " " Cobalt Copper " " Copper Gold " " Gold Iron " " Iron Lead " " Lead Manganese " " Manganese Mercury " " Mercury Molybdena[35] " " Molybdena Nickel " " Nickel Platina " " Platina Silver " " Silver Tin " " Tin Tungstein[36] " " Tungstein Zinc " " Zinc

Salifiable simple Earthy Substances[37]

Notes

Étienne Bonnot de Condillac (1715-1780) was a French philosopher and associate of Rousseau, Diderot, and the Encyclopedists. His La Logique (1780) stressed the importance of language as a tool in scientific and logical reasoning.

Lavoisier makes an excellent point, but he overstates it. Clearly ones ideas are not strictly limited or determined by one's language. New ideas must exist before new terms can be coined to express those ideas; thus new ideas can be formed and even to some extent described under the sway of older language. Also, new terms can only be defined by reference to pre-existing terms. Sometimes new terms are not necessary, as old terms absorb new meanings. For example, I hope that the selections in this book show to some extent how the terms "atom" and "element" have changed in meaning over time. Having made these points, I do not wish to minimize the ability of new terminology to help the mind to run along the path of new insights, or to prevent it from falling into old misconceptions.

Note that Lavoisier does not say merely that we ought not believe any idea but what follows immediately and necessarily from experiment, we ought not even form the idea. This statement shows a wariness of hypotheses common to many early scientists and natural philosophers. Compare Newton's, "I frame no hypotheses; for ... hypotheses ... have no place in experimental philosophy." [in Bartlett 1980] Hypotheses had no part in the empirical methodology of Francis Bacon (1561-1626; see portrait at National Portrait Gallery, London), which emphasized collection and classification of facts. This aversion to hypotheses is too not surprising if one considers that empiricists were attempting to distance themselves from rationalism. Later formulations of the scientific method, however, acknowledge the utility of hypotheses, always treated as provisional, in both suggesting experiments and interpreting them.

Lavoisier was not the last to observe that children are born scientists who learn by experience.

Lavoisier's choice of mathematics as an example may strike a modern reader as odd. While mathematics has long served as an example of the kind of certainty to which scientists aspire ("mathematical certainty"), it is now seen as based on axioms, not empirically based. Such mathematical systems as non-Euclidean geometry, which seemed to disagree with observed reality, had not yet been constructed at the time of Lavoisier's writing, though.

A table of affinities was a summary of a great deal of information on chemical reactions. It lists what substances react chemically with a given substance, often in order of the vigor or extent of the reaction. (If substance A reacted more strongly than substance B with a given material, then substance A was said to have a greater affinity than B for that material.) View a table of affinities by Étienne-François Geoffroy (1672-1731).

In Lavoisier's mind, it makes no sense to jump to this summary table without first describing the various substances and their characteristic reactions. The proper role of descriptive chemistry in the chemical curriculum continues to be a topic of debate in chemical education. Apparently Lavoisier would be quite sympathetic to the charge that introductory courses emphasize unifying principles at the expense of descriptive chemistry.

This is certainly an optimistic statement! Two hundred years later chemistry has developed to an extent Lavoisier could not have imagined, yet it is a rare and foolish chemist who expects the science to exhaust its possibilities for discovery within a lifetime.

Bergman, Scheele, De Morveau, and Kirwan were all contemporaries of Lavoisier. The Swedish chemist Carl Wilhelm Scheele had a hand in the discovery of oxygen, chlorine, and manganese. The Swedish chemist and mineralogist Torbern Bergman made contributions to analytical chemistry and the classification of minerals. Richard Kirwan was an Irish chemist and a defender of the phlogiston theory.

The influence of the ancients was on the decline when Lavoisier wrote these words, but he does not exaggerate the importance of their thought. Remember that he is still concerned about their influence more than a century after The Sceptical Chymist and more than two millennia after the death of Aristotle. (See chapters 1 and 2.) The simplicity of ancient ideas of matter would continue to have an influence on chemists well after Lavoisier's time, particularly as the number of chemical elements grew. (See chapter 10.)

Johann Joachim Becher (1635-1682) and Georg Ernst Stahl (1660-1734) were the two men most closely associated with the phlogiston theory. Lavoisier was largely responsible for dislodging and discrediting the notion that combustion and respiration involved a loss of a subtle material called phlogiston. (See chapter 5.) Lavoisier makes light of their ideas here, but the theory, though incorrect, was not as nonsensical as it may now appear.

Notice the pragmatism of Lavoisier's approach: he suggests, in essence, forgetting about the ultimate building blocks of matter. This was a prudent recommendation, for he had no way of addressing that subject empirically (which is why he dismisses it as metaphysical). He continues by suggesting that chemists turn their attention to what they can observe empirically, the ultimate products of chemical analysis. The definition of an element as a body which cannot be broken down further by chemical analysis is an operational one: as the techniques of chemical analysis improved, then substances scientists had any right to regard as elements could change.

At first, this definition of element appears to be similar to that of Boyle. (See chapter 2, note 9.) However, Boyle seemed not to consider elementary substances which were not components of all compound matter.

Lavoisier's table of simple bodies, reproduced below the preface, follows this prescription approximately, but not exactly. (See note 33 below.)

See note 34 below on names of metals.

Thus, where possible the name of a chemical substance should not simply be an arbitrary word, but should give some information about the substance. This principle is particularly evident in the modern systematic nomenclature of organic compounds: the name enables one who knows the rules of nomenclature and some organic chemistry to draw the structural formula of a compound from its name. (See IUPAC 1979, 1993.) The principle is also evident in the nomenclature of inorganic compounds [IUPAC 1971], the class of compounds Lavoisier's nomenclature primarily addresses. It is least evident in modern names of the elements, many of which are named after important scientists (e.g. curium, mendelevium, rutherfordium) or places important to the discoverers (e.g. polonium). (See Ringnes 1989 for etymology of elements' names.) Ironically, Lavoisier coined the name for an element central to his contributions to chemistry, a name of Greek origin chosen to convey information about the element which turned out to be incorrect. The name "oxygen" means "acid former," for Lavoisier believed that oxygen was a component of all acids.

Already we see the close connection Lavoisier envisioned between the language of chemistry and the content of the science. The system of naming compounds depends on classifying those compounds. Compounds belonging to the same class would have similar names. The name would also reflect the chemical composition of the substance.

So the classes of compounds included acids, oxides, sulfides, and the like. To specify which acid, a particular name was added, e.g. nitrous acid. Different suffixes distinguished between similar particular names (such as sulfuric and sulfurous--the -ic suffix applying to the more highly oxidized form).

What Lavoisier has in mind is a class of materials now called carbides, inorganic compounds of a metal and carbon ("charcoal"). But the examples he gives are not carbides. Steel is an alloy (a mixture or solution of metals, and therefore not a chemical compound of definite proportions); in particular, steel is principally iron with some carbon and sometimes other metals (such as chromium or manganese). Although plumbago has been used to refer to a variety of lead-containing substances (as might be guessed from the root plumb-), it also (as here) refers to the substance now called graphite, the form of carbon commonly used for pencil "leads."

Again in the case of salts we see the nomenclature embodying the principles of the chemical theory of the day. A salt was seen as a compound of an acid and a base, and an acid itself a compound of an acidifiable part and an acidifying part. The acidifying part, whatever its nature, was believed to be common to all acids; since it would not distinguish one salt from another, it does not appear in the name of the salt. The salts, then, carry the name of the acidifiable piece and the base with which it combines.

Pompholix was a crude (i.e., not very pure) zinc oxide (ZnO), sometimes known by the more pleasant but hardly more informative name flowers of zinc. Phagadenic water was a corrosive liquid used to cleanse ulcers; phagadenic refers to a spreading or "eating" ulcer. Colcothar is a brownish-red mixture containing primarily ferric oxide (Fe 2 O 3 ) with some calcium sulfate (CaSO 4 ). [ Oxford 1971]

Oil of vitriol is sulfuric acid, a viscous liquid. Butter of arsenic (arsenic trichloride) is an oily liquid; and butter of antimony (antimony trichloride) is a colorless deliquescent solid. In one sense, these names are informative, for they suggest the physical appearance of the substances they name; they are, however, also misleading in the sense Lavoisier points out.

Lavoisier recognizes that even the most rationally designed nomenclature would be useless if chemists chose not to use it. A language is one of the most visible signs of a people and culture; naturally, efforts to tamper with it can meet with disapproval. Thus Lavoisier pays at least nominal attention to aesthetic and cultural considerations, noting just above that the new terms sound no more "barbarous" than some technical terms then in existence. In a similar vein, he makes a concession to linguistic conservatism still further above, where he indicates that he does not propose to displace familiar names, at least for elements. And here he concedes that one ought not lightly to tamper with language, but that in doing so he is responding to a need and a demand.

Chemistry curricula in general devote little time to the history of the science, and that little usually consists of anecdotes scattered among other material. Discoverers of laws and elements may be mentioned; the pathways of discovery, however, let alone false steps on those pathways, almost never are. (See, however, Giunta 2001.) In my opinion, the teaching of scientific process (as opposed to content) suffers as a result. The emphasis on current content to the exclusion of historical material, however, itself has a long history and such distinguished advocates as Lavoisier.

The standards for crediting others for their ideas, particularly when they are similar to one's own, were not as stringent in Lavoisier's time as in our own. And yet Lavoisier was criticized even by contemporaries for failing to give what they believed to be sufficient credit. For instance, Joseph Priestley did not believe Lavoisier gave him sufficient credit for the discovery of "dephlogisticated air" (oxygen) when he described his own similar experiments [Conant 1957]. And Lavoisier's failure to credit James Watt and Henry Cavendish for their insights into the compound nature of water were a part of the sometimes rancorous "water controversy" [Ihde 1964]. See chapters 4 and 6 for articles on these subjects.

The first part of the treatise deals with gases, caloric, and the combustion of elements, so it truly contains the work most closely associated with Lavoisier.

Indeed, these words, which advocate empirical observation over rationalism as the source of reliable knowledge, apply to any science.

Light and caloric are not found on modern tables of elements because they are even matter, let alone elements of material bodies. Although a wave theory of light had been proposed by this time (by Christiaan Huygens), Newton's corpuscular (particle) theory was widely accepted until the 19 th century. Similarly, until the 19 th century, heat was widely believed to be a material, a fluid which flowed out of hot bodies and into cold ones (even though mechanical theories of heat with a Newtonian pedigree also existed at this time). See chapter 5, note 17 for a description of Lavoisier's thinking about heat and fire.)

As mentioned above, the name oxygen means "acid former," for Lavoisier believed (incorrectly) that oxygen was a component of all acids. Oxygen was a relatively recently discovered substance, and it did not have a standard name. The various names used for it are descriptive, but clumsy. "Dephlogisticated air" is particularly objectionable, for it described oxygen in terms of the phlogistion theory, which Lavoisier was in the process discrediting.

The name azote and the current name nitrogen were both used in English from the time of Lavoisier into the 19 th century. Azote means "lifeless," for breathing nitrogen does not sustain life.

Hydrogen means "water former," for water results from the burning of hydrogen. (See chapter 6.) Hydrogen was one of several gases discovered in the 18 th century. The names then in use for it were informative, denoting its flammability.

I.e., substances which can be oxidized (combined with oxygen).

These three radicals or "roots" had not yet been isolated or properly characterized. The fluoric radical, now called fluorine, is the root of fluorspar and other fluorine-containing minerals. Fluorine is very difficult to separate from its compounds, and is a very reactive and dangerous gas in its elemental form. This gas was not isolated until 1886. The boracic radical, now called boron, is the root of the mineral borax (Na 2 B 4 O 7 ); boron was not isolated until 1808. [Weeks & Leicester, 1968]

Muriatic acid was the name then in use for what we call hydrochloric acid or hydrogen chloride, HCl. Chlorine, the element which distinguishes this acid from others, was discovered by Carl Wilhelm Scheele; however, he named it oxymuriatic acid, believing it to be a compound containing oxygen. Muriatic radical, then, was the name for the hypothetical element believed to be combined with oxygen in oxymuriatic acid. Muriatic, by the way, means "pertaining to ... brine or salt" [ Oxford 1971]; the salt of muriatic acid is common table salt, sodium chloride (NaCl).

Lavoisier had good reason to expect that these radicals would be isolated, for their compounds had been known for a long time; however, the fluoric and boracic radicals were, strictly speaking, hypothetical substances at this time, and the basis of muriatic acid had already been isolated but he did not recognize it as elementary. Had he kept strictly to the principle of considering a substance an element if it could not be further decomposed, then Lavoisier should also have included "oxymuriatic acid" (undoubtedly by a different name) among the elements; as it was, chlorine was named and recognized to be elementary only in 1810 [Davy 1810, 1811]. Although we can see, with hindsight, that Lavoisier was incorrect, it was by no means obvious at the time. Chlorine had been prepared from reactions with substances that do contain oxygen, for example from pyrolusite (MnO 2 ) in Scheele's original isolation and from aqueous muriatic acid (HCl).

Until the phlogiston theory was discarded, metals were commonly regarded as compounds of their minerals ("earths") and phlogiston. This idea was incorrect, but it seemed to make sense, for the earths or ores seemed to be more fundamental than the metals. After all, the earths were found readily in nature, but to obtain the metals one had to heat the earths strongly in the presence of charcoal. In any event, the metal came to be known as the regulus of the mineral; for example, the name antimony was originally applied to an antimony sulfide, Sb 2 S 3 , and the metal was called regulus of antimony. Lavoisier drops the term regulus, giving the simple body (the metal) the simple, unmodified term.

The element is now known as molybden um . Similarly Lavoisier's platina is now called platin um . The ending is important: the -um ending now denotes a metal, while the -a ending denotes an oxide of that metal.

Now tungsten.

All of these "earthy substances" proved to be compounds. Their elements were first isolated in the early 19 th century. Of course, Lavoisier was justified in including them among his elements, for none of them had yet been broken down into anything simpler. Two interesting omissions from this table are soda and potash, comounds of sodium and potassium known since antiquity but whose elementary metals had not yet been extracted. One might have expected Lavoisier to list such substances either here or with the hypothesized radicals (note 33).

Chalk frequently refered to calcium carbonate (CaCO 3 ), but apparently it was also used for calcium oxide [ Oxford 1971]. Magnesia is magnesium oxide, MgO. (See note 35.) Epsom salt is magnesium sulfate, MgSO 4 , so named for the location (an English town) of a mineral spring from which the salt was obtained. Barytes is barium oxide, BaO. Argill or argil is an aluminum-containing potters' clay. Alum is a transparent aluminum-containing mineral, AlK(SO 4 ) 2 .12H 2 O. Humphry Davy was the first to isolate calcium, magnesium, barium, [Davy 1808b] sodium, and potassium [Davy 1808a]; he was also a co-discoverer of boron [Davy 1809] and he recognized chlorine to be an element (note 34). Vitrifiable means able to be made into glass; indeed, common glass is mainly silicon dioxide. [Weeks & Leicester 1968]

References

John Bartlett (Emily Morison Beck, ed.), Familiar Quotations , 15 th ed. (Boston: Little, Brown, 1980), p. 313

, 15 ed. (Boston: Little, Brown, 1980), p. 313 James Bryant Conant, "The Overthrow of the Phlogiston Theory" in James Bryant Conant, ed., Harvard Case Histories in Experimental Science , Vol. 1, (Cambridge, MA: Harvard, 1957), p. 89

, Vol. 1, (Cambridge, MA: Harvard, 1957), p. 89 Humphry Davy, "The Bakerian Lecture: On Some New Phenomena of Chemical Changes Produced by Electricity, Particularly the Decomposition of the Fixed Alkalies, and the Exhibition of the New Substances Which Constitute Their Bases; And on the General Nature of Alkaline Bodies," Philosophical Transactions of the Royal Society 98 , 1-44 (1808a)

, 1-44 (1808a) Humphry Davy, "Electro-Chemical Researches, on the Decomposition of the Earths; With Observations on the Metals Obtained from the Alkaline Earths, and on the Amalgam Procured from Ammonia," Philosophical Transactions of the Royal Society 98 , 333-70 (1808b)

, 333-70 (1808b) Humphry Davy, "The Bakerian Lecture: An Account of Some New Analytical Researches on the Nature of Certain Bodies, Particularly the Alkalies, Phosphorus, Sulphur, Carbonaceous Matter, and the Acids Hitherto Undecompounded; With Some General Observations on Chemical Theory," Philosophical Transactions of the Royal Society 99 , 39-104 (1809)

, 39-104 (1809) Humphry Davy, "Researches on the Oxymuriatic Acid, Its Nature and Combinations; And on the Elements of the Muriatic Acid. With Some Experiments on Sulphur and Phosphorus, Made in the Laboratory of the Royal Institution," Philosophical Transactions of the Royal Society 100 , 231-57 (1810)

, 231-57 (1810) Humphry Davy, "The Bakerian Lecture: On Some of the Combinations of Oxymuriatic Gas and Oxygene, and on the Chemical Relations of These Principles, to Inflammable Bodies," Philosophical Transactions of the Royal Society 101 , 1-35 (1811)

, 1-35 (1811) Carmen J. Giunta, "Using History to Teach Scientific Method: the Role of Errors," Journal of Chemical Educcation 78 , 623-627 (2001).

, 623-627 (2001). Aaron J. Ihde, The Development of Modern Chemistry (New York: Dover, 1964, 1984), pp. 69-73.

(New York: Dover, 1964, 1984), pp. 69-73. International Union of Pure and Applied Chemistry (IUPAC), Nomenclature of Inorganic Chemistry , 2 nd ed. (London: Butterworths, 1971)

, 2 ed. (London: Butterworths, 1971) International Union of Pure and Applied Chemistry (IUPAC), Nomenclature of Organic Chemistry , 4 th ed. (Oxford and New York: Pergamon Press, 1979); on-line version

, 4 ed. (Oxford and New York: Pergamon Press, 1979); on-line version International Union of Pure and Applied Chemistry (IUPAC), A Guide to IUPAC Nomenclature of Organic Compounds (Recommendations 1993) , (Oxford: Blackwell , 1993); on-line version

, (Oxford: Blackwell , 1993); on-line version Antoine Lavoisier, Elements of Chemistry (1789), translation by Robert Kerr (Edinburgh, 1790); annotated excerpts above.

(1789), translation by Robert Kerr (Edinburgh, 1790); annotated excerpts above. Henry M. Leicester & Herbert S. Klickstein, A Source Book in Chemistry 1400-1900 (New York: McGraw Hill, 1952), pp. 180-92

(New York: McGraw Hill, 1952), pp. 180-92 Oxford English Dictionary (Oxford: Oxford, 1971)

(Oxford: Oxford, 1971) Vivi Ringnes, "Origin of the Names of Chemical Elements," Journal of Chemical Educcation 66 , 731-8 (1989)

, 731-8 (1989) Mary Elvira Weeks & Henry M. Leicester, Discovery of the Elements , 7 th ed. (Easton, PA: Journal of Chemical Education, 1968)

Elements and Atoms