Collingwood is set to poach Carlton captain Brianna Davey in a stunning AFLW development.

Fox Footy’s Jon Ralph has reported that Davey approached the Pies about making the move and has been lured by a significant offer.

Davey won Carlton’s best and fairest on Thursday night, sharing the honour with first-year midfielder Maddison Prespakis.

The 24-year-old nearly joined Collingwood last year, before new-Blues coach Daniel Harford convinced her to stay.

“My first job was to make sure Brianna Davey was going to stay because I was at Collingwood as an assistant and knew that Collingwood were coming hard for Bri," Harford told SEN's Whateley in March.

“So I was on the other side of that negotiation, not intimately involved, but seeing it happen, and I knew that there was a real opportunity that the Magpies might get Bri."

Collingwood will need to trade for Davey in order to acquire her. They currently hold the number one pick in the draft, but the AFL is yet to confirm the final selection order.

Davey tore her ACL last season, returning this season and leading Carlton to a Grand Final loss.

Collingwood meanwhile won only the one game and sacked coach Wayne Siekman.

Follow @NicNegrepontis