Material Safety Data Sheet



Crude Oil

Section 1 - Chemical Product and Company Identification

MSDS Name: Crude Oil

Catalog Numbers: SRS951020, SRS951500, SRS952020, SRS952500, SRS953020, SRS953500

Synonyms: Base oil; coal liquid; coal oil; petroleum ether, fuel; rock oil; seneca oil.

Company Identification:

Fisher Scientific

1 Reagent Lane

Fair Lawn, NJ 07410

For information, call: 201-796-7100

Emergency Number: 201-796-7100

For CHEMTREC assistance, call: 800-424-9300

For International CHEMTREC assistance, call: 703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS 8002-05-9 Petroleum distillates (naphtha) 100 232-298-5

Section 3 - Hazards Identification



EMERGENCY OVERVIEW

Appearance: dark yellow to brown or green-black liquid.

Warning! Flammable liquid and vapor. Causes eye and skin irritation. May cause lung damage. May cause central nervous system effects. May cause dermatitis.

Target Organs: Central nervous system.





Potential Health Effects

Eye: Causes eye irritation.

Skin: Exposure may cause irritation characterized by redness, dryness, and inflammation.

Ingestion: Aspiration hazard. Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.

Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. High vapor concentrations may cause drowsiness.

Chronic: Prolonged or repeated skin contact may cause dermatitis.

Section 4 - First Aid Measures



Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.

Ingestion: Do not induce vomiting. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Notes to Physician: Treat symptomatically and supportively.

Antidote: None reported. Section 5 - Fire Fighting Measures





General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extremely flammable liquid and vapor. Vapor may cause flash fire.

Extinguishing Media: Use foam, dry chemical, or carbon dioxide. Water may be ineffective. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained.

Flash Point: -6.7 - 32.2 deg

Autoignition Temperature: Not applicable.

Explosion Limits, Lower:Not available.

Upper: Not available.

NFPA Rating: (estimated) Health: ; Flammability: ; Instability: Section 6 - Accidental Release Measures





General Information: Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Section 7 - Handling and Storage





Handling: Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Prevent build up of vapors to explosive concentration. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Section 8 - Exposure Controls, Personal Protection





Engineering Controls: Use explosion-proof ventilation equipment. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.

Exposure Limits Chemical Name ACGIH NIOSH OSHA - Final PELs Petroleum distillates (naphtha) none listed 350 mg/m3 TWA 1100 ppm IDLH none listed

OSHA Vacated PELs: Petroleum distillates (naphtha): 400 ppm TWA; 1600 mg/m3 TWA

Personal Protective Equipment

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.

Skin: Wear appropriate gloves to prevent skin exposure.

Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced. Section 9 - Physical and Chemical Properties





Physical State: Liquid

Appearance: dark yellow to brown or green-black

Odor: mild odor

pH: Not available.

Vapor Pressure: Not available.

Vapor Density: >1.0

Evaporation Rate:Not available.

Viscosity: Not available.

Boiling Point: < 0 - >1093.3 deg C

Freezing/Melting Point:-60 deg C

Decomposition Temperature:Not available.

Solubility: Insoluble in water.

Specific Gravity/Density:0.780-0.970

Molecular Formula:Not available.

Molecular Weight:Not available. Section 10 - Stability and Reactivity





Chemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.

Conditions to Avoid: Incompatible materials, ignition sources, excess heat.

Incompatibilities with Other Materials: May explode with nitrogen tetroxide, potential violent reaction with strong oxidizers. This material is peroxizable and may form crystals capable of exploding after prolonged storage.

Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.

Hazardous Polymerization: Has not been reported. Section 11 - Toxicological Information





RTECS#:

CAS# 8002-05-9: SE7175000; SE7449000

LD50/LC50:

CAS# 8002-05-9:

Draize test, rabbit, eye: 100 mg Mild;

Draize test, rabbit, skin: 500 mg/24H Moderate;

Oral, mouse: LD50 = >4300 mg/kg;

Oral, rat: LD50 = >4300 mg/kg;

.



Carcinogenicity:

CAS# 8002-05-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.



Epidemiology: No data available.

Teratogenicity: No data available.

Reproductive Effects: No data available.

Mutagenicity: No data available.

Neurotoxicity: No data available.

Other Studies: Section 12 - Ecological Information





Ecotoxicity: No data available. This chemical is expected to cause some oxygen depletion in aquatic systems. It has a low potential to affect aquatic systems. It has a low potential to affect aquatic organisms, secondary waste treatment microorganisms and the germination of some plants. It has a moderate potential to affect the germination and growth of some plants.

Environmental: This chemical does not bioconcentrate.

Physical: No information found.

Other: No information found. Section 13 - Disposal Considerations



Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.

RCRA P-Series: None listed.

RCRA U-Series: None listed. Section 14 - Transport Information



US DOT Canada TDG Shipping Name: Not regulated as a hazardous material No information available. Hazard Class: UN Number: Packing Group:

Section 15 - Regulatory Information



US FEDERAL



TSCA

CAS# 8002-05-9 is listed on the TSCA inventory.

Health & Safety Reporting List

None of the chemicals are on the Health & Safety Reporting List.

Chemical Test Rules

None of the chemicals in this product are under a Chemical Test Rule.

Section 12b

None of the chemicals are listed under TSCA Section 12b.

TSCA Significant New Use Rule

None of the chemicals in this material have a SNUR under TSCA.

CERCLA Hazardous Substances and corresponding RQs

None of the chemicals in this material have an RQ.

SARA Section 302 Extremely Hazardous Substances

None of the chemicals in this product have a TPQ.

Section 313 No chemicals are reportable under Section 313.

Clean Air Act:

This material does not contain any hazardous air pollutants.

This material does not contain any Class 1 Ozone depletors.

This material does not contain any Class 2 Ozone depletors.

Clean Water Act:

None of the chemicals in this product are listed as Hazardous Substances under the CWA.

None of the chemicals in this product are listed as Priority Pollutants under the CWA.

None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

OSHA:

None of the chemicals in this product are considered highly hazardous by OSHA.

STATE

CAS# 8002-05-9 can be found on the following state right to know lists: New Jersey, Pennsylvania, Minnesota, Massachusetts.



California Prop 65



California No Significant Risk Level: None of the chemicals in this product are listed.



European/International Regulations

European Labeling in Accordance with EC Directives

Hazard Symbols:

Not available.

Risk Phrases:



Safety Phrases:



WGK (Water Danger/Protection)

CAS# 8002-05-9: 1

Canada - DSL/NDSL

CAS# 8002-05-9 is listed on Canada's DSL List.

Canada - WHMIS

not available.

This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.

Canadian Ingredient Disclosure List

Section 16 - Additional Information

