By Michael Fitzpatrick

Science reporter, BBC News

Frozen depositories are giving up methane to the sea Scientists have uncovered what appears to be a further dramatic increase in the leakage of methane gas that is seeping from the Arctic seabed. Methane is about 20 times more potent than CO2 in trapping solar heat. The findings come from measurements of carbon fluxes around the north of Russia, led by Igor Semiletov from the University of Alaska at Fairbanks. "Methane release from the East Siberian Shelf is underway and it looks stronger than it was supposed [to be]," he said. Professor Semiletov has been studying methane seepage in the region for the last few decades, and leads the International Siberian Shelf Study (ISSS), which has launched multiple expeditions to the Arctic Ocean. The preliminary findings of ISSS 2009 are now being prepared for publication, he told BBC News. Methane seepage recorded last summer was already the highest ever measured in the Arctic Ocean. High seepage Acting as a giant frozen depository of carbon such as CO2 and methane (often stored as compacted solid gas hydrates), Siberia's shallow shelf areas are increasingly subjected to warming and are now giving up greater amounts of methane to the sea and to the atmosphere than recorded in the past. METHANE HYDRATES Methane gas is trapped inside a crystal structure of water-ice The gas is released when the ice melts, normally at 0C At higher pressure, ie under the ocean, hydrates are stable at higher temperatures This undersea permafrost was until recently considered to be stable. But now scientists think the release of such a powerful greenhouse gas may accelerate global warming. Higher concentrations of atmospheric methane are contributing to global temperature rise; this in turn is projected to cause further permafrost melting and the release of yet more methane in a feedback loop. A worst-case scenario is one where the feedback passes a tipping point and billions of tonnes of methane are released suddenly, as has occurred at least once in the Earth's past. Such sudden releases have been linked to rapid increases in global temperatures and could have been a factor in the mass extinction of species. According to a report by the US National Oceanic and Atmospheric Administration (Noaa), the springtime air temperature across the region in the period 2000-2007 was an average of 4C higher than during 1970-1999. That is the fastest temperature rise on the planet, claims the university. The recent thaw over the last decade means that some of the large reserve of carbon from organic material such as dead animals and plants in sediments is now being released into the sea and into our atmosphere. Trapped below that is the methane hydrate now warming and leaking through holes in the defrosting sediments. 1. Methane hydrate is stable at high pressure and low temperature 2. Nearer the surface, where water pressure is lower, hydrates break down earlier than at greater depth as temperatures rise 3. Gas rises from the sea-bed in plumes of bubbles - some of it dissolves before it reaches the surface 4. The ISSS team says it has detected methane breaking the ocean surface

Previously it was thought much of this gas was absorbed into the sea. But according to a recent report that Professor Semiletov and his team compiled for the environmental group WWF, the shallow depth of arctic shelves means that methane is reaching the atmosphere without reacting to become CO2 dissolved in the ocean. Professor Semiletov's fellow researcher aboard the Russian icebreaker that carries the ISSS team each year is Professor Orjan Gustafsson from Stockholm University in Sweden. He said that methane measured in the atmosphere around the region is 100 times higher than normal background levels, and in some cases 1,000 times higher. 'No alarm' Despite the high readings, Professor Gustafsson said that so far there was no cause for alarm, and stressed that further studies were still necessary to determine the exact cause of the methane seepage. "It is important now to understand how fast it is being released and how much is being released," he said. However, there is a real fear that global warming may cause Siberia's subsea permafrost to thaw. Some estimates put the amount of carbon trapped in shelf permafrost at 1,600 billion tonnes - roughly twice as much carbon as in the atmosphere now. The release of this once captive carbon from destabilised ocean sediments and permafrost would have catastrophic effect on our climate and life on Earth, warn the scientists.



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